Sterically Hindered Ligands and Studies of Their Biomimetic Metal Complexes

位阻配体及其仿生金属配合物的研究

• 批准号: 9208192
• 负责人: Patricia Traylor
• 金额: $ 13.27万
• 依托单位: University of San Diego
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1992
• 资助国家: 美国
• 起止时间: 1992-12-15 至 1997-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9208192&HistoricalAwards=false
• 关键词: Sterically; Hindered; Ligands; Studies; Their

This research will focus on the synthesis of hindered bidentate ligands designed to enforce unusual coordination numbers and/or geometries around a metal (copper). The work seeks to provide better models for understanding the chemical and spectroscopic properties of metalloproteins such as azurin. %%% With this RUI award, the Synthetic Organic Program is supporting the research of Dr. Patricia S. Traylor of the Department of Chemistry at the University of San Diego. The focus of the research will be to use hindered ligands to help understand the extraordinary spectra and properties of important classes of metalloenzymes and to involve undergraduates in a meaningful research experience.

本论文的研究重点是受阻双齿配体的合成 设计用于强制执行异常配位数的配体和/或 金属（铜）周围的几何形状。 这项工作旨在提供 更好的模型来理解化学和光谱 金属蛋白质如天青蛋白的性质。 %%% 有了这个RUI奖，合成有机计划是 支持Patricia S博士的研究。第1001章：最后一次 圣地亚哥大学化学系。 的 研究的重点将是使用受阻配体来帮助 了解的非凡光谱和性质 金属酶的重要类别，并涉及 本科生在一个有意义的研究经验。