Gel Permeation Chromatograph

该装置将用于研究超临界流体中聚合物的(生物)催化合成。具体地说，用于合成聚对苯二甲酸乙二酯、聚谷氨酸乙二酯、并进行多肽合成。此外，使用超临界流体作为传统聚合的溶剂也是可行的。以前关于丙烯酸酯(生物)催化酯交换反应的工作已经产生了一套优化酶促反应的通用指南超临界环境中的流程。利用这些指南，本项目将建立(生物)催化合成芳香族和脂肪族聚酯的可行性。

This equipment is to be used for investigations of the (bio)catalytic synthesis of polymers in supercritical fluids. Specifically, the identification of enzymes for the synthesis of poly(ethylene terephthalate), poly(ethylene glutamate), and peptide synthesis is to be carried out. In addition, the use of supercritical fluids as solvents for traditional polymerization is to done. Previous work on the (bio)catalytic transesterification of acrylates has produced a set of general guidelines for the optimization of enzymatic processes in supercritical environments. Using these guidelines, this project is to establish the feasibility of the (bio)catalytic synthesis of aromatic and aliphatic polyesters.