Midgap States in Tantalum Triselenide

三硒化钽中的中能隙态

• 批准号: 9214491
• 负责人: Joseph Brill
• 金额: $ 1.83万
• 依托单位: University of Kentucky Research Foundation
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1993
• 资助国家: 美国
• 起止时间: 1993-03-15 至 1994-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9214491&HistoricalAwards=false
• 关键词: Midgap; States; Tantalum; Triselenide

The presence of soliton states with energies below the single particle gap in charge-density-wave (CDW) conductors is of great theoretical importance, but as yet, they have not been measured directly. Such states should have fractional charge, and are expected to exist at equilibrium in commensurate or nearly commensurate systems. They are also implicated in the conversion between CDW and normal (band) carriers at electrical contacts. Two experiments are proposed to optically observe such states in TaS3. They combine the expertise of investigators from the Institute of Radio Engineering and Electronics, Russian Academy of Sciences and the University of Kentucky; the experiments will be undertaken at the University of Kentucky. Bolometric specta will be taken as a function of uniaxial strain to look for changes in the equilibrium density and energies of solitons. Transmission spectra near electrical contacts will be taken as functions of CDW current. %%% Experimental and theoretical research on charge-density-wave (CDW) conductors such as tantalum trisulfide (TaS3) continues to be of current interest. Like superconductors, these materials exhibit collective electron transport; i.e. the current is carried by coherent motion of all the electrons. Unlike superconductors, however, this motion is strongly affected by impurities and other crystalline defects, leading to a number of unique and surprising properties. Defects in the CDW itself, (called "solitons") have energies less than the CDW energy gap. Such defects are necessary to convert "normal" electrons into CDW electrons at electrical contacts; furthermore, fractional electric charge (i.e. less than the charge of a single electron) is localized at each soliton. However, such defect states have never been directly observed. This proposal describes two experiments, to be carried out at the University of Kentucky. The work is a collaboration between the host institution and the Institute of Radio Engineering and Electronics (Moscow), to look for "midgap" soliton states in TaS3 using infrared spectroscopy. In the first experiment, changes in the spectra caused by straining the sample, which changes the defect concentration, will be sought. In the second experiment, changes in spectra near electrical contacts as functions of current will be explored.

电荷密度波(CDW)导体中能量低于单粒子禁带的孤子态的存在具有重要的理论意义，但尚未被直接测量到。这样的状态应该有分数电荷，并预计在相称或接近相称的系统中处于平衡状态。它们还与电触点上的CDW和正常(带)载流子之间的转换有关。提出了两个实验来光学观察TaS3中的这种状态。他们结合了来自俄罗斯科学院无线电工程和电子研究所和肯塔基大学的研究人员的专业知识；实验将在肯塔基大学进行。玻耳曼光谱将作为单轴应变的函数来寻找孤子的平衡密度和能量的变化。电触点附近的透射谱将作为CDW电流的函数。三硫化钽(TaS3)等电荷密度波(CDW)导体的实验和理论研究仍然是当前的研究热点。像超导体一样，这些材料表现出集体的电子传输；也就是说，电流由所有电子的相干运动携带。然而，与超导体不同的是，这种运动受到杂质和其他晶体缺陷的强烈影响，导致了一些独特而令人惊讶的性质。CDW本身的缺陷(称为“孤子”)的能量小于CDW的能隙。这些缺陷是在电接触处将“正常”电子转换为CDW电子所必需的；此外，分数电荷(即小于单个电子的电荷)在每个孤子处局域。然而，这种缺陷状态从未被直接观察到。该提案描述了将在肯塔基大学进行的两个实验。这项工作是主办机构和莫斯科无线电工程与电子研究所合作的，目的是利用红外光谱学寻找TaS3中的“中能隙”孤子状态。在第一个实验中，将寻求通过对样品进行应变而引起的光谱变化，从而改变缺陷浓度。在第二个实验中，我们将探索电触点附近光谱随电流的变化。