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Integration of High Field Fourier Transform Nuclear Magnetic Resonance Spectrometry into the Undergraduate Chemistry Curriculum

Integration of High Field Fourier Transform Nuclear Magnetic Resonance Spectrometry into the Undergraduate Chemistry Curriculum
高场傅里叶变换核磁共振波谱分析融入本科化学课程
批准号:
9250660
负责人:
Rhoda Craig
金额:
$9.1万
依托单位:
依托单位国家:
美国
项目类别:
Standard Grant
财政年份:
1992
资助国家:
美国
项目状态:
已结题
起止时间:
1992-07-01 至 1994-12-31

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中文摘要
翻译
化学系正在购买一台高场傅立叶 变换核磁共振谱仪 以综合的方式进行本科教学, 从低年级到高年级。 八 涉及专业和非专业的讲座/实验室课程是 受到技术的影响。 碱性13 C和1H- 三维和二维(COSY,HETCOR,INADEQUATE)NMR 在大二有机化学中介绍了技术 课程使用已知的天然产品和学生的进步 有机定性中未知物的结构解析 分析. 平衡常数和反应速率 在大三的物理化学中测量。 在 高年级学生学习分子中的感应衰变 结构与反应性课程与多核核磁共振 光谱学在高级无机化学课程 在参与高级无机化学研究期间, 项目 无机化学关注分子结构 主族和过渡金属化合物的测定, 分子重排和电子结构,而 在有机化学项目涉及两个动力学 有机化合物的分子重排和 复杂生物活性天然产物的结构解析。
英文摘要
The Department of Chemistry is acquiring a high field fourier transform nuclear magnetic resonance spectrometer for undergraduate instruction in an integrated manner from the lower division through the senior course level. Eight lecture/laboratory courses involving majors and non-majors are being affected by the technology. Basic 13C and 1H one- dimensional and two-dimensional (COSY, HETCOR, INADEQUATE) NMR techniques are introduced in the sophomore Organic Chemistry course using known natural products and the students progress to structure elucidation of unknowns in Organic Qualitative Analysis. Equilibrium constants and reaction rates are being measured in Physical Chemistry during the junior year. At the senior level students study induction decay in the Molecular Structure and Reactivity course and multinuclear NMR spectroscopy in both the Advanced Inorganic Chemistry course and during participation in Senior Inorganic Chemistry Research Projects. Inorganic Chemistry focusses on molecular structure determination of main group and transition metal compounds, molecular rearrangements, and electronic structure, while projects in Organic Chemistry involve both the kinetics of molecular rearrangements of organic compounds and the structural elucidation of complex bioactive natural products.
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