U.S.-France Cooperative Research: Effects of Peripheral Substituents on Physical-Chemical Characteristics of CPD I Analogs

美法合作研究：外围取代基对 CPD I 类似物理化特性​​的影响

• 批准号: 9314422
• 负责人: Avram Gold
• 金额: $ 0.73万
• 依托单位: University of North Carolina at Chapel Hill
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1994
• 资助国家: 美国
• 起止时间: 1994-04-01 至 1997-09-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9314422&HistoricalAwards=false
• 关键词: U.S.; France; Cooperative; Research; Effects

9314422 Gold This three-year award, which supports U.S.-France-German cooperative research in inorganic chemistry, involves four laboratories in the U.S. and Europe. The principal investigators are: Avram Gold of the University of North Carolina; James Terner of Virginia Commonwealth University; Raymond Weiss of the Universite Louis Pasteur in Strasbourg, France; and A. X. Trautwein, Director of the Institute of Physics, University of Lubeck in Germany. The objective of their research is to study the effects of peripheral substituents on the molecular and electronic structure of synthetic, high valent iron porphyrin. The laboratories will contribute complementary techniques towards characterizing the starting complexes and the high-valent species. The U.S. investigators are experts in the synthesis, generation, and characterizations of these compounds using NMR and resonance Raman spectroscopy. This is complemented by French expertise in synthesis and German expertise in x-ray crystallography and electrochemical studies. The project will advance understanding of high valent iron porphyrin, which is an important intermediary in the catalysis of enzymatic systems. ***

小行星9314422 这个为期三年的奖项，支持美国-法德无机化学合作研究，涉及美国和欧洲的四个实验室。主要研究人员是：北卡罗来纳州大学的Avram Gold、弗吉尼亚联邦大学的James Terner、法国斯特拉斯堡的Louis Pasteur大学的Raymond韦斯和A. X. 德国吕贝克大学物理研究所所长特劳特温说。 他们的研究目标是研究外围取代基对合成高价铁卟啉的分子和电子结构的影响。 这些实验室将为确定起始络合物和高价物质的特性提供补充技术。 美国研究人员是使用NMR和共振拉曼光谱法合成、生成和表征这些化合物的专家。 法国在合成方面的专业知识和德国在X射线晶体学和电化学研究方面的专业知识对此进行了补充。 该项目将促进对高价铁卟啉的理解，这是酶系统催化的重要中介。 ***