Lone Pairs, Hydrogen Bonds and Ionic Solvation

孤电子对、氢键和离子溶剂化

• 批准号: 9420739
• 负责人: Charles Perrin
• 金额: $ 39.3万
• 依托单位: University of California-San Diego
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1994
• 资助国家: 美国
• 起止时间: 1994-12-01 至 1998-11-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9420739&HistoricalAwards=false
• 关键词: Lone; Pairs; Hydrogen; Bonds; Ionic

Professor Perrin of the University of California San Diego will continue his investigations on the effects of nonbonding electron pairs, on reactions, the asymmetry of hydrogen bonds in solution and the effects of ion solvation on stereoelectronic properties. Each of these has subtle but significant effects on reaction rates and stereochemistry. While they are reported in the sense of basic research, the implications are of wide significance in organic, physical, theoretical and biochemistry. There are subtle electronic effects caused by nonbonded electrons, hydrogen bonds and solvation of ions which have significant consequences in life processes as well as chemical manipulations. Thus, the results of this investigation have broad spectrum potential impacting fundamental and life sciences.

加州大学圣地亚哥分校的佩林教授将继续研究非键电子对对反应的影响、溶液中氢键的不对称性以及离子溶剂化对立体电子性质的影响。 其中每一个对反应速率和立体化学都有微妙但显着的影响。 虽然它们是在基础研究意义上进行报道的，但其影响在有机、物理、理论和生物化学方面具有广泛的意义。 非键合电子、氢键和离子溶剂化会产生微妙的电子效应，这些效应对生命过程和化学操作产生重大影响。 因此，这项研究的结果具有影响基础科学和生命科学的广泛潜力。