Reactivity and Stereoelectronic Effects in Fluorinated and Charged Radical Systems

摘要CHE-9521971威廉·R·多尔比尔1995年9月25日佛罗里达大学在有机动力学项目的资助下，佛罗里达大学的威廉·R·多尔比尔教授将继续研究含氟自由基。将进行各种实验，其中一些实验是与其他机构的高级调查人员以及佛罗里达州的合作进行的。测定含氟自由基的加成、抽提和环化反应的绝对速率是要完成的主要任务。这些实验将加深对氟作为取代基在自由基化学中的作用的理解。这项工作具有工业意义，因为氟化合物具有独特和有利的性质(例如特氟龙)。有些是商业物品，这些基础研究可能会导致制备此类化合物的新方法。

ABSTRACT CHE-9521971 William R. Dolbier 25 September 1995 University of Florida With funding from the Organic Dynamics Program Professor William R. Dolbier of the University of Florida will continue studies of fluorine-containing free radicals. A variety of experiments will be undertaken, some in collaboration with senior investigators at other institutions as well as at Florida. The determination of absolute rates in additions, abstractions, and cyclizations of fluorine- containing free radicals is the major task to be performed. These experiments will increase the understanding of the effect of fluorine as a substituent in free radical chemistry. The work has industrial significance in that fluorine compounds possess unique and advantageous properties (e.g. Teflon). Some are articles of commerce and these fundamental studies may lead to new ways of preparing such compounds.