Synthesis and Chemistry of Novel Fluorocarbons

新型氟碳化合物的合成与化学

• 批准号: 9530352
• 负责人: David Lemal
• 金额: $ 32.35万
• 依托单位: Dartmouth College
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1996
• 资助国家: 美国
• 起止时间: 1996-05-01 至 2000-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9530352&HistoricalAwards=false
• 关键词: Synthesis; Chemistry; Novel; Fluorocarbons

The focus of this research entails the synthesis and investigation of the chemistry of an array of highly fluorinated target molecules, all of which have skeletons of twelve or fewer carbon atoms. Ab initio quantum mechanical calculations will be employed as both a guide to the design of experiments and as an aid in the interpretation of experimental results. With this renewal award, the Synthetic Organic Program is supporting the research of Dr. David M. Lemal of the Department of Chemistry at Dartmouth College. Professor Lemal will focus his work on the synthesis and investigation of the chemistry of an array of highly fluorinated compounds. Replacement of the hydrogens in organic molecules by fluorine results in dramatic differences in both properties and chemical behavior. As a result, fluorocarbon chemistry has great commercial importance.

本研究的重点是综合和调查 高度氟化的目标分子阵列的化学性质， 其骨架含有12个或更少的碳原子。 从头量子 机械计算将被用来指导设计， 实验，并作为实验结果的解释援助。 有了这个更新奖，合成有机计划正在支持 大卫博士的研究化学系的勒马尔在 达特茅斯学院。 勒莫教授将把他的工作重点放在 以及对一系列高度氟化的 化合物. 氟取代有机分子中的氢原子 导致性质和化学行为的显著差异。 因此，碳氟化合物化学具有很大的商业重要性。