Multiply Bonded Organosilicon Compounds

本研究的重点是新型有机硅的合成 具有不寻常化学键的化合物。 目标包括Silynes， 硅丙二烯和硅烷酮。 赛络阴离子和二价阴离子与之反应 与过渡金属反应以获得新型的噻咯-金属络合物， 将研究稳定的亚甲硅烷基的化学反应。 还有， 用与碳化硅或元素混合的碳的汽化 磷，新富勒烯碳笼，含硅或磷 笼形框架中的原子，将被制备。 有了这个更新奖， 合成有机计划正在支持罗伯特博士的研究 威斯康星州大学化学系的西边。 韦斯特教授将把工作重点放在合成新型的 有机硅化合物含有不寻常的化学键合模式。 将要构建的分子测试了硅的能力极限 与碳结合，并有望产生有趣的化学物质， 特性.

The focus of this research is the synthesis of new organosilicon compounds that have unusual chemical bonding . Targets include silynes, silaallenes and silamones. Silole anions and dianions with be reacted with transition metals to obtain new types of silole-metal complexes and the chemical reactions of stable silylenes will be investigated. Also, by vaporization of carbon mixed with silicon carbide or elemental phosphorus, new fullerene carbon cages, containing silicon or phosphorus atoms in the cage framework, will be prepared. With this renewal award, the Synthetic Organic Program is supporting the research of Dr. Robert West of the Department of Chemistry at the University of Wisconsin. Professor West will focus his work on the synthesis of new types of organosilicon compounds that contain unusual chemical bonding patterns. The molecules to be constructed test the limits of the ability of silicon to bond with carbon and are expected to have interesting chemical properties.