Mathematical Models of Phase Transitions in Quartz

石英相变的数学模型

• 批准号: 9704621
• 负责人: Robert Rogers
• 金额: $ 13.5万
• 依托单位: Virginia Polytechnic Institute and State University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1997
• 资助国家: 美国
• 起止时间: 1997-08-01 至 2001-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9704621&HistoricalAwards=false
• 关键词: Mathematical; Models; Phase; Transitions; Quartz

DMS-9704621 Rogers This grant funds a program of mathematical investigations of the alpha-beta phase transition in quartz. In unstressed quartz this transition occurs at about 574 degrees Centigrade, at which point a quartz crystal undergoes a change in shape, volume, and symmetry. The high temperature beta-phase has larger volume and higher symmetry than the low-temperature alpha-phase. The alpha-beta transition can be accompanied by an interesting triangular microstructure that is quite different from the layered microstructures that are usually found in shape memory alloys and ferromagnetic materials. An interesting mathematical feature of the problem is that the microstructure is describe by the oscillation of a scalar order parameter. Order parameters have been used in many other studies of phase transitions, but they are usually hard to measure and are defined in fairly fuzzy physical terms. On the other hand, the order parameter in quartz is well defined physically and there are good techniques for measuring it. Thus, it provides an excellent test case for mathematical models using order parameters. The proposers plan to use techniques of differential equations, the calculus of variations, scientific computation, and bifurcation theory to study both standard models for quartz and models that they will propose. %%% When a material undergoes a drastic change in its fundamental properties we say it has undergone a "phase transition." The obvious examples are freezing and melting, evaporation and condensation, but more subtle atomic rearrangements are covered by the term as well. Despite the technological importance of such material changes, the mathematical theory describing them is nowhere near as well developed as theory describing the motion, deformation, and thermal properties of materials. This grant funds a program of mathematical investigations of a phase transition in quartz. The transition is caused by changing temperature and occurs at about 574 degrees Centigrade. At this temperature, a quartz crystal undergoes a change in shape, volume, and symmetry. The transition can be accompanied by an interesting microscopic triangular pattern that is quite different from the layered patterns that are usually found in shape memory alloys and ferromagnetic materials. An understanding of these microscopic patterns (called "microstructures") is widely believed to be a key to the understanding of the phase transitions that they accompany. There are a number of reasons for focusing on this particular phase transition. Quartz has a number of important industrial applications such as oscillators and optical waveguides. In addition, the transition in quartz is usually described mathematically by a quantity called an "order parameter." Order parameters have been used in many other types of phase transitions, but they are usually hard to measure and are defined in fairly fuzzy physical terms. On the other hand, the order parameter in quartz is well defined physically and there are good techniques for measuring it. Thus, quartz provides an excellent test case for mathematical models using order parameters. ***

Dms-9704621罗杰斯这笔赠款资助了一个关于石英中阿尔法-贝塔相变的数学研究项目。在无应力的石英中，这种转变发生在摄氏574度左右，此时石英晶体的形状、体积和对称性都会发生变化。高温β相比低温α相具有更大的体积和更高的对称性。α-β转变可能伴随着有趣的三角形微结构，这与形状记忆合金和铁磁材料中常见的层状微结构截然不同。这个问题的一个有趣的数学特征是，微观结构用标量序参数的振荡来描述。有序参数已经被用于许多其他相变研究，但它们通常很难测量，并且定义在相当模糊的物理术语中。另一方面，石英中的有序参数在物理上定义得很好，也有很好的测量技术。因此，它为使用序参数的数学模型提供了一个很好的测试用例。提出者计划使用微分方程组、变分法、科学计算和分叉理论的技术来研究石英的标准模型和他们将提出的模型。%当一种物质的基本性质发生剧烈变化时，我们说它经历了“相变”。最明显的例子是冻结和融化、蒸发和凝结，但这个术语也涵盖了更微妙的原子重排。尽管这种材料变化在技术上很重要，但描述它们的数学理论远远没有描述材料的运动、变形和热性质的理论发展得好。这笔赠款资助了一项关于石英相变的数学研究计划。这种转变是由温度变化引起的，发生在大约574摄氏度。在这个温度下，石英晶体的形状、体积和对称性都会发生变化。这种转变可能伴随着一种有趣的微观三角形图案，这种图案与形状记忆合金和铁磁材料中常见的层状图案截然不同。人们普遍认为，对这些微观图案(称为“微结构”)的理解是理解它们所伴随的相变的关键。关注这一特定的相变有许多原因。石英具有许多重要的工业应用，如振荡器和光波导器件。此外，石英中的转变通常用一种叫做“序参数”的量来描述。序参量曾被用于许多其他类型的相变，但它们通常很难测量，并且定义在相当模糊的物理术语中。另一方面，石英中的有序参数在物理上定义得很好，也有很好的测量技术。因此，Quartz为使用序参数的数学模型提供了一个很好的测试用例。***