Rational Design of Supramolecular Assemblies via Incommensurate Geometries and Coordination Numbers

通过不相称的几何形状和配位数合理设计超分子组装体

• 批准号: 9709621
• 负责人: Kenneth Raymond
• 金额: $ 33万
• 依托单位: University of California-Berkeley
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1997
• 资助国家: 美国
• 起止时间: 1997-07-01 至 2000-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9709621&HistoricalAwards=false
• 关键词: Rational; Design; Supramolecular; Assemblies; via

This award supports research in the laboratory of Professor Kenneth N. Raymond of the Department of Chemistry at the University of California at Berkeley. Using biological examples as models, this research endeavors to develop symmetry-driven supramolecular assemblies. It is the goal of the research to precisely define what can be programmed into a ligand in terms of predetermined symmetry based linkages and to exploit this to develop new chemistry based on supramolecular self-assembly. Large, supramolecular structures of tetrahedra, cubes and dodecahedra will be synthesized with metal ions at the vertices and organic linkers along the edges. Symmetry-based principles developed in this work will be generally applicable to the preparation of other nanostructures.

该奖项支持Kenneth N. 加州大学化学系的雷蒙德在 伯克利 本研究以生物实例为模型， 来开发超分子驱动的组装体 它的目标是 精确定义什么可以被编程到配体中的研究， 基于预定对称性的连接的术语，并利用这一点来 开发基于超分子自组装的新化学。 四面体、立方体和 将在顶点处合成具有金属离子的十二面体， 沿着边缘沿着的有机连接体。 基于对称性的原则， 这项工作将普遍适用于其他 纳米结构。