Conjugated Polymers as Materials for Solid State Lasers

共轭聚合物作为固态激光器的材料

• 批准号: 9730126
• 负责人: Alan Heeger
• 金额: $ 30.9万
• 依托单位: University of California-Santa Barbara
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1998
• 资助国家: 美国
• 起止时间: 1998-05-01 至 2001-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9730126&HistoricalAwards=false
• 关键词: Conjugated; Polymers; Materials; Solid; State

9730126 Heeger Semiconducting polymers offer important advantages as potential laser materials, e.g., High photoluminescence efficiency (PL), low self-absorption, emission wavelengths that span the visible spectrum, easily processed into optical quality thin films, and electrically pumped in a diode configuration. The high PL efficiency and large cross-section for stimulated emission persist to high concentrations. In contrast to traditional laser dyes, conjugated polymers function as high gain laser materials in the solid state, neat and undiluted. To obtain lower thresholds and to generate coherent laser light, it is necessary to incorporate the conjugated polymer into a resonant structure. The goal of this research is to achieve low threshold optically pumped polymer lasers through improvements in materials and materials processing and through the creation of novel resonant structures. With sufficiently low thresholds, lasing structures fabricated from semiconducting polymers can be developed as cw lasers. For example they could be pumped with conventional light sources, or with blue-emitting LEDs (e.g. using the InGaN technology), or with solar radiation (solar powered lasers!). To accomplish this goal, significant improvements in the polymer materials are required to enable the high-Q resonant structures that are needed. These improvements and the related achievement of high-Q resonant structures with conjugated polymers as the gain media are the goals of the proposed research. The actual work will include: measurements of gain and loss in photopumped semiconducting polymer films; materials development including fabrication of high quality, low-loss optical thin film waveguides and expansion into new conjugated systems (new PPV derivatives, polyfluorene derivatives and spiro-conjugated materials); development of cladding materials; and evaluation of these conjugated materials in microcavities, in distributed feedback structures and in `whispe ring gallery mode' structures (micro-disks and micro-rings). %%% This research will provide fundamental understanding and potentially new and improved devices in the area of laser materials and electrically active polymers. ***

9730126希格 半导体聚合物作为潜在的激光材料提供了重要的优点，例如，高光致发光效率（PL）、低自吸收、发射波长跨越可见光谱、易于加工成光学质量薄膜并在二极管配置中进行电泵浦。 高的PL效率和大的受激发射截面持续到高浓度。 与传统的激光染料相比，共轭聚合物在固态、纯的和未稀释的情况下用作高增益激光材料。 为了获得较低的阈值和产生相干激光，有必要将共轭聚合物引入共振结构中。 本研究的目标是通过材料和材料加工的改进以及通过创建新的谐振结构来实现低阈值光泵浦聚合物激光器。 在足够低的阈值下，半导体聚合物制成的激光结构可以发展为连续激光器。 例如，它们可以用传统光源泵浦，或者用蓝色发光LED（例如使用InGaN技术）泵浦，或者用太阳辐射泵浦（太阳能激光器！）。 为了实现这一目标，需要对聚合物材料进行重大改进，以实现所需的高Q谐振结构。 这些改进和共轭聚合物作为增益介质的高Q谐振结构的相关成就是拟议研究的目标。 实际工作将包括：测量半导体聚合物薄膜的增益和损耗;材料开发，包括制造高质量，低损耗的光学薄膜波导和扩展到新的共轭系统（新的PPV衍生物、聚芴衍生物和螺共轭材料）;包覆材料的开发;以及在微腔、分布反馈结构和“whispe ring gallery mode”结构（微盘和微环）中评估这些共轭材料。 这项研究将为激光材料和电活性聚合物领域提供基本的理解和潜在的新的和改进的设备。 ***