Electrophilic Activation of Metal Complexes Through Bimetallic Complex Formation

通过形成双金属配合物对金属配合物进行亲电活化

• 批准号: 9805255
• 负责人: David Burkey
• 金额: $ 4万
• 依托单位: San Diego State University Foundation
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1998
• 资助国家: 美国
• 起止时间: 1998-04-01 至 2001-03-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9805255&HistoricalAwards=false
• 关键词: Electrophilic; Activation; Metal; Complexes; Through

This starter grant award of the Chemistry Division to San Diego State University supports the research of Professor David Burkey. The theme of the research is the use of electrophilic activation in manipulating the reactivity of transition-metal complexes. A bimetallic complex will be generated by binding a second metal species to a ligand of the original complex. The incoming metal species will withdraw electron density from an aromatic substituent at the site of attachment in the complex, thereby modifying the nature and reactivity of the original metal complex. New types of bimetallic complexes with imido, carbyne, acetylene, and isocyanide groups as the bridging ligands in these studies function as excellent electronic bridges, maximizing cooperative interactions between the two metals. The reactivity of the bimetallic complexes will be examined with emphasis on identifying and exploiting new types of reactivity unavailable to the individual metal complexes. Formation of bimetallic complexes such as studied in this project may be an effective means of producing catalysts as well as in developing new organometallic materials which exhibit desirable optical and magnetic properties. Such compounds can serve as models for new types of metal-containing polymers with other desirable material properties.

这个化学部门的启动补助金奖给圣地亚哥州立大学 大学支持大卫伯基教授的研究。 主题 这项研究是使用亲电激活在操纵 过渡金属配合物的反应性。 一个复合体将是 通过将第二金属物质结合到原始金属物质的配体上而产生 复杂. 进入的金属物质将从金属吸收电子密度。 在络合物中的连接位点处的芳族取代基，从而 改变了原始金属络合物的性质和反应性。 新 与亚氨基、碳炔、乙炔和 在这些研究中，作为桥连配体的异氰化物基团的功能是 良好的电子桥梁，最大限度地提高合作之间的互动 这两种金属。 该络合物的反应性将是 研究重点是确定和利用新的 单个金属络合物不可用的反应性。 如本项目所研究的金属络合物的形成， 一种生产催化剂以及开发新的 具有所需光学和磁性的有机金属材料 特性. 这些化合物可以作为新型的生物化学的模型。 具有其它所需材料性质的含金属聚合物。