US-India Cooperative Research: Host-Guest Chemistry in Polyoxometalates (V and Mo): Synthesis, Structure, Electrochemical and Magnetic Properties

美印合作研究：多金属氧酸盐（V和Mo）的主客体化学：合成、结构、电化学和磁性

• 批准号: 9911983
• 负责人: M. Stanley Whittingham
• 金额: $ 2.08万
• 依托单位: SUNY at Binghamton
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2000
• 资助国家: 美国
• 起止时间: 2000-05-01 至 2005-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9911983&HistoricalAwards=false
• 关键词: US; India; Cooperative; Research; Host

INT-9911983WhittinghamDescription: This award is for the US-India Collaborative Research: Host-Guest Chemistry in Polyoxometalates (V and Mo): Synthesis, Structure, Electrochemical and Magnetic Properties. Collaborators Stanley Whittingham, State University of New York at Binghamton and Indian chemist Arunachalam Ramanan, Indian Institute of Technology will undertake research in solid state chemistry leading to an understanding of the parameters involved in hydrothermal synthesis of transition metal oxides and framework materials. Structure control is critical for an intelligent design of battery and sensor materials. The major emphasis of this project will be placed on vanadium and molybdenum oxides. These host materials will be characterized for their ability to be intercalated by a variety of guest ions and molecules, and their chemical and physical properties will be determined using x-ray, electrochemical, and magnetic/electrical measurements as well as the standard analytical techniques. Scope: This collaboration adds an international component to research currently supported by the Division of Materials Research (DMR-9810198). Whittingham has made important contributions in the areas of hydrothermal synthesis, structural solid state chemistry, and battery materials; Ramanan has made major contributions in the areas of polyoxometalate chemistry, hydrothermal chemistry and chemistry involving intercalation compounds. The PIs have established a record of high quality joint research. This project will accelerate the research programs at both institutions and will impact graduate and undergraduate students. This research has high potential to impact the development of batteries and sensors.

INT-9911983 Whittingham描述：该奖项是为美国-印度合作研究：聚氧乙烯酸酯（V和Mo）的主客体化学：合成，结构，电化学和磁性。 合作者Stanley Whittingham，州立大学的纽约宾厄姆顿分校和印度化学家Arunachalam Ramanan，印度理工学院将进行固态化学研究，从而了解过渡金属氧化物和框架材料的水热合成所涉及的参数。 结构控制对于电池和传感器材料的智能设计至关重要。 该项目的重点将放在钒和钼的氧化物。 这些主体材料的特征在于它们被各种客体离子和分子插入的能力，并且它们的化学和物理性质将使用X射线、电化学和磁/电测量以及标准分析技术来确定。 范围：这项合作为目前由材料研究部（DMR-9810198）支持的研究增加了国际组成部分。 惠廷厄姆在水热合成、结构固态化学和电池材料领域做出了重要贡献;拉曼南在聚氧乙烯酸盐化学、水热化学和涉及插层化合物的化学领域做出了重大贡献。 PI已经建立了高质量的联合研究记录。 该项目将加速这两个机构的研究计划，并将影响研究生和本科生。 这项研究很有可能影响电池和传感器的发展。