U.S.-Switzerland Cooperative Research: Chiral Hypervalent Iodine Chemistry

美国-瑞士合作研究：手性高价碘化学

• 批准号: 9976636
• 负责人: Andrew French
• 金额: $ 1.8万
• 依托单位: Albion College
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1999
• 资助国家: 美国
• 起止时间: 1999-08-15 至 2002-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9976636&HistoricalAwards=false
• 关键词: U.S.; Switzerland; Cooperative; Research; Chiral

9976636French This three-year award supports US-Swiss collaborative research in organic chemistry between Andrew French of Albion College and Thomas Wirth of the University of Basel. The research involves evaluation of chiral hypervalent iodine compounds as asymmetric reagents. The investigators propose to synthesize and characterize new iodinane reagents, their intermediates, and the product of their reactions with compounds containing carbon-carbon double bonds. NMR, MS and elemental analysis will be applied in these studies.This project initiates a new collaboration with Swiss researchers and provides an international research opportunity to an assistant professor at a predominantly US undergraduate institution and to his undergraduate students. Students will gain research experiences in organic chemistry, including multistep synthesis of chiral nonracemic compounds, and in synthetic methodology. The project takes advantage of Swiss expertise in the area of chiral hypervalent iodine compounds.

9976636FRENCH这三年奖支持Albion学院的Andrew French和巴塞尔大学的Thomas Wirth之间的有机化学合作研究。 该研究涉及评估手性高价值碘化合物作为不对称试剂。 研究人员建议合成并表征新的碘宁试剂，它们的中间体以及其反应与含有碳碳双键的化合物的乘积。 NMR，MS和元素分析将在这些研究中应用。本项目与瑞士研究人员启动了新的合作，并为主要是我们本科生和他的本科生的助理教授提供了国际研究机会。 学生将获得有机化学方面的研究经验，包括手性非流行化合物的多步合成以及合成方法。 该项目在手性高估碘化合物领域充分利用瑞士专业知识。