POWRE: Use of Deuterium Labeling and Substituent Effects as Mechanistic Probes of the [1,3] Carbon Migration in the Bicyclo[3.2.0]hept-2-ene System.

POWRE：利用氘标记和取代基效应作为双环[3.2.0]庚-2-烯系统中[1,3]碳迁移的机理探针。

• 批准号: 0075097
• 负责人: Phyllis Leber
• 金额: $ 6.84万
• 依托单位: Franklin and Marshall College
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2000
• 资助国家: 美国
• 起止时间: 2000-07-15 至 2002-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0075097&HistoricalAwards=false
• 关键词: POWRE; Use; Deuterium; Labeling; Substituent

This POWRE award to Dr. Phyllis Leber will allow her to supplement a sabbatical leave from Franklin and Marshall College to extend her repertory of mechanistic probes of organic chemical reactions. She will learn dynamic isotopic dilution kinetic procedures in the laboratory of John E. Baldwin at Syracuse University and apply these techniques to a study of substituent effects in organic chemical rearrangement reactions at Franklin and Marshall College.

Phyllis Leber博士的这一POWRE奖将使她能够补充富兰克林和马歇尔学院的休假，以扩展她对有机化学反应的机械探针的研究。她将学习动态同位素稀释动力学程序在实验室的约翰E。鲍德温在锡拉丘兹大学和应用这些技术的取代基效应在有机化学重排反应的研究在富兰克林和马歇尔学院。