CAREER: Electrically Active Organic/Inorganic Hybrid Materials

职业：电活性有机/无机杂化材料

• 批准号: 0134032
• 负责人: Zhonghua Peng
• 金额: $ 40万
• 依托单位: University of Missouri-Kansas City
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2002
• 资助国家: 美国
• 起止时间: 2002-02-01 至 2008-01-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0134032&HistoricalAwards=false
• 关键词: CAREER; Electrically; Active; Organic; Inorganic

Using a modular building block strategy, conjugated molecules and polymers containing polyoxometalate (POM) clusters covalently linked in a variety of architectures will be synthesized for the first time. The proposed research stems from a recent discovery of a novel reaction protocol which allows the efficient and facile functionalization of POM clusters with a variety of aromatic amines and the recent demonstration that functionalized POM clusters can undergo Pd-catalyzed organic coupling reactions. The proposed hybrid systems not only represent truly new and novel classes of functional materials where strong electronic interactions exist between delocalized d-electrons, they are also expected to possess extremely interesting electrical and optical properties. Preliminary studies clearly demonstrate the suitability of the proposed modular building block approach.%%%The educational goal of this Career Development plan is threefold: to be an excellent mentor producing creative and productive scientists, an efficient instructor promoting chemical science education, and a passionate community member assisting the local school district with its science education. A new teaching style has been brought to the Organic Chemistry class and students' response has been extremely positive. Strong efforts have been and will continue to be made towards training science teachers for the local community and exposing young high school students to research laboratories. The proposed research is geared toward discovery of new chemistry and innovative materials. The planned educational activities represent combined efforts in effective education and community involvement. They form a unified career plan, a journey toward becoming a creative researcher and an effective educator.

使用模块化构建块策略，将首次合成在各种体系结构中共价链接的共轭分子和含有聚氧化物（POM）簇的聚合物。 拟议的研究源于最近发现的一种新型反应方案，该方案允许具有多种芳香胺的POM簇的有效且容易的功能化，并且最近证明了功能化的POM簇可以经历PD催化的有机偶联反应。 所提出的杂种系统不仅代表了真正的新型和新颖的功能材料，在这些功能材料中，在Decalized D电子之间存在强烈的电子相互作用，而且还有望拥有非常有趣的电气和光学特性。 初步研究清楚地表明了拟议的模块化构建障碍方法的适当性。%% %%该职业发展计划的教育目标是三重：成为一名出色的导师，创造了创造性和生产性的科学家，有效的促进化学科学教育的有效教练，以及一位热情的社区成员，协助当地学区进行科学教育。 有机化学班级已采取了一种新的教学风格，学生的反应非常积极。 已经并且将继续为当地社区培训科学教师，并将年轻的高中生研究实验室进行巨大努力。 拟议的研究旨在发现新的化学和创新材料。 计划的教育活动代表了有效的教育和社区参与方面的综合努力。 他们构成了统一的职业计划，是成为一名创意研究人员和有效的教育者的旅程。