CAREER: Career Development Plan: Integrated Research and Education Activities

职业：职业发展计划：综合研究和教育活动

• 批准号: 0222511
• 负责人: G. Tayhas Palmore
• 金额: $ 6.98万
• 依托单位: Brown University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2001
• 资助国家: 美国
• 起止时间: 2001-10-01 至 2004-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0222511&HistoricalAwards=false
• 关键词: CAREER; Career; Development; Plan; Integrated

The focus of this research is to design molecules to self assemble into one- and two-dimensional supramolecular motifs or aggregates that will serve as scaffolds with which to control three-dimensional structures. Cyclic diamides are targeted as the molecular building blocks . Among those to be studied are 2,5-diketopiperazines, 3,6-dioxo-1,2,4-triazines and 3,6-dioxo-1,2,4,5-tetrazines. The robust one-dimensional `tapes` obtained from these building blocks will then be used as precursors of interesting solid state materials. The educational focus of the project is the integration of supramolecular chemistry into the undergraduate curriculum. With this Faculty Early Development (CAREER) award, the Organic and Macromolecular Chemistry Program is supporting the research and educational activities of Dr. G. Tayhas R. Palmore of the Department of Chemistry at the University of California, Davis. Professor Palmore will focus her research efforts on understanding how the self assembly of molecules into supramolecular motifs can be used to control solid state structure. Self assembly of nanostructures promises to be one of the most powerful approaches to device miniaturization. The aim of the proposed educational activities is to stimulate interdisciplinary discussion and research in supramolecular chemistry and to integrate supramolecular chemistry into the undergraduate curriculum.

这项研究的重点是设计分子自组装成 一维和二维超分子基序或聚集体， 用作控制三维结构的支架。 环状二酰胺被作为分子构建块。 之间 待研究的是2，5-二酮哌嗪、3，6-二氧代-1，2，4-三嗪 和3，6-二氧代-1，2，4，5-四嗪。 坚固的一维“磁带” 从这些构建块中获得的，然后将被用作 有趣的固态材料。 项目的教育重点 是将超分子化学融入到大学生的 课程。 有了这个教师早期发展（职业生涯）奖， 有机和高分子化学计划正在支持这项研究 G博士的教育活动。泰哈斯河部门的Palmore 他是加州大学戴维斯分校的化学教授。 帕尔莫教授 她将把研究重点放在了解自我组装是如何 分子的超分子基序可以用来控制固体 国家结构。 纳米结构的自组装有望成为 最强大的设备小型化方法。 的目的 建议的教育活动是促进跨学科 在超分子化学的讨论和研究，并整合 超分子化学纳入本科课程。