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How Do Exchange and Correlation Affect the Dynamics of Electron Transfer? Experimental and Theoretical Studies of Model Two-Electron Systems in Solution

How Do Exchange and Correlation Affect the Dynamics of Electron Transfer? Experimental and Theoretical Studies of Model Two-Electron Systems in Solution
交换和关联如何影响电子转移动力学?
批准号:
0240776
负责人:
Benjamin Schwartz
金额:
$32.6万
依托单位国家:
美国
项目类别:
Continuing Grant
财政年份:
2003
资助国家:
美国
项目状态:
已结题
起止时间:
2003-03-15 至 2007-02-28

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英文摘要
In this project, funded by the Experimental Physical Chemistry Program of the Chemistry Division, The PI will carry out a research program to investigate the effects of correlation and exchange on the solvation dynamics and adiabatic couplings that control electron transfer. Ongoing work on the charge-transfer-to-solvent (CTTS) reaction of solvated alkali metal atoms will be continued with femtosecond techniques. New pump-probe experiments will be used to identify the transient intermediates formed during CTTS and for mapping out the dynamics of solvent dissipation. The research will be conducted with the assistance of graduate students. They will be trained in a forefront area of contemporary physical chemistry in preparation for advanced studies or entry into the country's workforce.
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The Behavior of Solvated Electrons in the Presence of Electrolytes: Using Simulation and Experiment to Determine the Hydrated Electron's Structure from Competitive Ion Pairing
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    2247583
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    Standard Grant
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    $52.5万
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    2023
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The Effects of Driving Force, Morphology and Anion Separation on Carrier Mobility in Doped Conjugated Polymers
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    2105896
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    $60.5万
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    2021
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Understanding the Structure and Dynamics of Solvated Electrons Using Ultrafast Spectroscopy and Quantum Simulation Methods
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    1856050
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    Continuing Grant
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    $50.0万
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    2019
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    Benjamin Schwartz
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Understanding the Structure and Dynamics of Solvated Electrons Using Ultrafast Spectroscopy and Mixed Quantum/Classical Molecular Dynamics Simulation
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    1565434
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    Standard Grant
  • 资助金额:
    $41.37万
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    2016
  • 负责人:
    Benjamin Schwartz
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