Research to Produce Pressures of 600 GPa or Higher on Hydrogen and to Produce Metallic Hydrogen

研究产生600 GPa或更高的氢气压力并生产金属氢

• 批准号: 0304745
• 负责人: Arthur Ruoff
• 金额: --
• 依托单位: Cornell University
• 依托单位国家: 美国
• 项目类别: Continuing grant
• 财政年份: 2003
• 资助国家: 美国
• 起止时间: 2003-05-15 至 2007-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0304745&HistoricalAwards=false
• 关键词: Research; Produce; Pressures; 600; GPa

This condensed matter physics project deals with molecular hydrogen subjected to ultrahigh pressures. The physical properties of hydrogen, one of the simplest elements or materials, are still not understood as a function of pressure. One fundamental question is whether it retains its insulating state or undergoes phase transitions to other, perhaps conducting or metallic states. One theory predicts a metallic transition near 450 GPa. Another theory suggests a transition to a near zero band gap semiconductor, near 400 GPa, subsequently converting to a cubic metal near 600 GPa. In previous work, the principal investigator has reached pressures of 560 GPa in other materials, but has been limited to 342 GPa in hydrogen, because hydrogen reacts with the diamond anvil cells required to reach ultrahigh pressures. A new hydrogen diffusion barrier has been developed that should reduce or eliminate this problem. Other technical advances, including reduction in the anvil tip diameter, suggest that the maximum attainable pressures may be increased by a factor of 1.4. Optical reflectivity measurements can be used to detect any transition to a semiconducting or metallic state. In addition, Meissner effect measurements will be made at pressure to detect a superconducting state. The research involves the training of post-doctoral associates in unique and cutting edge research techniques that will prepare the for careers in academe, industry and government. Hydrogen at ordinary pressures exists as a molecular gas, the molecule being formed by two hydrogen atoms held together by the prototypical chemical bond. However, this simple system contains much physics and is still not completely understood. One famous physicist, Victor Weiskopf, was quoted as saying, "we will not understand solid state physics until we understand solid hydrogen". Hydrogen can be cooled and compressed, first forming a liquid, and then a solid. It is these phases, particularly the solid phase that present considerable challenges to both theory and experiment to understand. The goal of this research is to use the latest diamond anvil techniques to achieve ultrahigh pressures to convert initially insulating solid hydrogen to a metallic, conducting state, and possibly even to a superconducting state. This will require reaching the unheard of static pressure of 600 GPa, which is far above the pressure at the center of the earth. It has been calculated that metallic hydrogen will be a superconductor with a very high Tc, possibly room temperature. This calculation has been given added credence by the recent findings of high Tc's in the low atomic number materials MgB2 at ambient pressure, and Li at high pressure. A discovery of superconductivity near room temperature in hydrogen would be a great stimulus to search for superconductivity in other low-Z materials. The research involves the training of post-doctoral associates in unique and cutting edge research techniques that will prepare them for careers in academe, industry and government.

这个凝聚态物理项目研究的是处于超高压下的氢分子。 氢是最简单的元素或材料之一，其物理性质仍然不被理解为压力的函数。 一个基本的问题是它是否保持其绝缘状态或经历相变到其他状态，可能是导电或金属状态。 一种理论预测在450 GPa附近发生金属转变。 另一种理论认为，在400 GPa附近，过渡到近零带隙半导体，随后在600 GPa附近转化为立方金属。 在以前的工作中，主要研究者已经在其他材料中达到了560 GPa的压力，但在氢气中被限制在342 GPa，因为氢气与金刚石砧座反应需要达到100 GPa的压力。 已经开发了一种新的氢扩散阻挡层，可以减少或消除这个问题。 其他技术进步，包括钉砧尖端直径的减小，表明可达到的最大压力可增加1.4倍。 光学反射率测量可用于检测到半导体或金属状态的任何转变。 此外，迈斯纳效应测量将在压力下进行，以检测超导状态。 该研究涉及在独特和尖端的研究技术，将准备在企业，工业和政府的职业生涯博士后助理的培训。 氢在常压下以分子气体的形式存在，分子由两个氢原子通过原型化学键结合在一起形成。 然而，这个简单的系统包含了许多物理学，仍然没有完全理解。 一位著名的物理学家维克托·韦斯科普夫曾说：“在我们理解固体氢之前，我们不会理解固体物理学”。 氢可以被冷却和压缩，首先形成液体，然后形成固体。 正是这些相，特别是固相，对理论和实验都提出了相当大的挑战。 这项研究的目标是使用最新的金刚石砧技术来实现超高压，将最初绝缘的固体氢转化为金属导电状态，甚至可能转化为超导状态。 这将需要达到闻所未闻的600 GPa的静压，这远远高于地球中心的压力。 据计算，金属氢将是一种具有很高Tc的超导体，可能是室温。 最近发现低原子序数材料MgB 2在常压下和Li在高压下的高温转变温度都很高，这一计算结果得到了进一步的证实。 氢在室温附近的超导性的发现将极大地刺激在其他低Z材料中寻找超导性。 该研究涉及对博士后助理进行独特和尖端研究技术的培训，这些技术将为他们在工业，工业和政府中的职业生涯做好准备。