Endohedral metallofullerenes - filled fullerene derivatives toward multifunctional reaction center mimics

内嵌金属富勒烯 - 填充富勒烯衍生物，用于模拟多功能反应中心

• 批准号: 163372219
• 负责人: Professor Dr. Dirk M. Guldi
• 金额: --
• 依托单位: Lehrstuhl für Physikalische Chemie I
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2010
• 资助国家: 德国
• 起止时间: 2009-12-31 至 2018-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/163372219?language=en
• 关键词: Endohedral; metallofullerenes; filled; fullerene; derivatives

The major thrust of the project is to explore for the first time the use of endohedral metallofullerenes as multifunctional electron acceptors / traps in an interdisciplinary fashion. Such fundamental investigations of new molecular architectures are essential for future technological applications. The design principles of novel hybrid materials/devices with high structural integrity should be as simple as possible. Thus, several available suitable functional building blocks will be combined with endohedral metallofullerenes, into multifunctional molecular architectures. These investigations will provide impetus and information for the development of, for instance, a new generation of solar cells.To implement this program, it is necessary to cover topics ranging from spectroscopic investigation and materials characterization to preparative efforts. The project will benefit from our existing expertise with organic hybrid materials and supramolecular systems. In particular, our experience with chromophores and fullerene derivatives, which are the basic constituents of the architectures envisaged, will be of great value.This proposal also provides a mechanism for interdisciplinary training of scientists and students, as its success requires cooperation among groups with different complementary expertise.

该项目的主要目标是首次以跨学科的方式探索内源性金属富勒烯作为多功能电子受体/陷阱的使用。这种对新分子结构的基础研究对未来的技术应用至关重要。具有高结构完整性的新型混合材料/器件的设计原则应尽可能简单。因此，一些可用的合适的功能构建块将与内源性金属富勒烯结合，形成多功能分子结构。这些研究将为诸如新一代太阳能电池的开发提供动力和信息。为了实现这一计划，有必要涵盖从光谱研究和材料表征到准备工作的主题。该项目将受益于我们现有的有机混合材料和超分子系统的专业知识。特别是，我们在发色团和富勒烯衍生物方面的经验，它们是所设想的结构的基本组成部分，将具有很大的价值。这一建议还为科学家和学生的跨学科培训提供了一种机制，因为它的成功需要具有不同互补专业知识的小组之间的合作。

项目成果

Bidirectional Electron Transfer Capability in Phthalocyanine-Sc3N@I(h)-C80 Complexes.

• DOI: 10.1021/jacs.5b06454
• 发表时间: 2015-10
• 期刊: Journal of the American Chemical Society
• 影响因子: 15
• 作者: O. Trukhina;M. Rudolf;G. Bottari;T. Akasaka;L. Echegoyen;T. Torres;D. Guldi

Taming C60 fullerene: tuning intramolecular photoinduced electron transfer process with subphthalocyanines

驯服 C60 富勒烯：用亚酞菁调节分子内光致电子转移过程

• DOI: 10.1039/c5sc00223k
• 发表时间: 2015
• 期刊: Chemical Science
• 影响因子: 8.4
• 作者: M. Rudolf;O. Trukhina;J. Perles;L. Feng;T. Akasaka;T. Torres;D.M. Guldi
• 通讯作者: D.M. Guldi