SGER: Metathesis-Doped Polyacetylene

SGER：复分解掺杂聚乙炔

• 批准号: 0320583
• 负责人: Michael Sponsler
• 金额: $ 10万
• 依托单位: Syracuse University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2003
• 资助国家: 美国
• 起止时间: 2003-07-01 至 2005-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0320583&HistoricalAwards=false
• 关键词: SGER; Metathesis; Doped; Polyacetylene

Michael Sponsler, Department of Chemistry, Syracuse University, is supported by the Inorganic, Bioinorganic and Organometallic Chemistry Program for studies of "metathesis-doped polyacetylene". He is incorporating metathesis-active ruthenium compounds into films of polyacetylene to determine the electronic properties of conjugated organometallic structures. By capping polyacetylene oligomers with ruthenium compounds, long-chain ruthenapolyenes and diruthenapolyenes can be prepared in viscous solution and thin films, where they should be stable. The conductivity of these films will be measured and correlated with various structural parameters. In a related component of this research, modified ruthenium complexes will be used to make connections between nanoscale and macroscale electronic components. This Small Grant for Exploratory Research (SGER) supports high risk/high impact research in molecular electronics and nanotechnology. This interdisciplinary project will also provide graduate and undergraduate students with training in these important areas.

锡拉丘兹大学化学系的Michael Sponsler得到了无机、生物无机和有机化学项目的支持，研究“易位掺杂的聚乙炔”。他正在将具有复分解活性的钌化合物掺入聚乙炔薄膜中，以确定共轭有机金属结构的电子性质。通过用钌化合物封端聚乙炔低聚物，可以在粘性溶液和薄膜中制备长链聚乙炔和二聚乙炔，其中它们应该是稳定的。这些薄膜的电导率将被测量，并与各种结构参数。在这项研究的相关组成部分中，改性钌络合物将用于连接纳米级和宏观级电子元件。探索性研究小额赠款（SGER）支持分子电子学和纳米技术的高风险/高影响研究。这个跨学科项目还将为研究生和本科生提供这些重要领域的培训。