Zero Electron Kinetic Energy Photoelectron Spectroscopy of Metal Association Complexes

金属缔合物的零电子动能光电子能谱

• 批准号: 0415682
• 负责人: Dong-Sheng Yang
• 金额: $ 33.56万
• 依托单位: University of Kentucky Research Foundation
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2004
• 资助国家: 美国
• 起止时间: 2004-08-01 至 2008-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0415682&HistoricalAwards=false
• 关键词: Zero; Electron; Kinetic; Energy; Photoelectron

In this project, funded by the Experimental Physical Chemistry Program of the Chemistry Division, Professor Dong-Sheng Yang of the University of Kentucky will investigate the electronic spectra, metal-ligand bonding, and molecular structures of gas-phase metal-aromatic complexes by means of Zero Electron Kinetic Energy (ZEKE) photoelectron spectroscopy. The metals are aluminum, copper, and scandium atoms, while the ligands are benzene, polycyclic aromatic hydrocarbons, and nitrogen-containing heterocycles. To be determined are the adiabatic ionization potentials, vibrational frequencies, bond energies, electronic states, and molecular structures. This information is critically needed for improving our understanding of metal bonding interactions that are important in organometallic compounds, biological systems, materials synthesis, and homogeneous catalysis, as well as in applications to industrial processes. Graduate and undergraduate students will participate in this research. They will thereby acquire knowledge and skills that prepare them for advanced studies or entry into the scientific/technological workforce.

在这个由化学系实验物理化学计划资助的项目中，肯塔基州大学的杨东升教授将利用零电子动能（ZEKE）光电子能谱研究气相金属-芳香族络合物的电子光谱、金属-配体键合和分子结构。 金属是铝、铜和钪原子，而配体是苯、多环芳烃和含氮杂环。 要确定的是绝热电离势，振动频率，键能，电子态和分子结构。 这些信息对于提高我们对金属键合相互作用的理解至关重要，这些相互作用在有机金属化合物，生物系统，材料合成和均相催化以及工业过程中的应用中非常重要。 研究生和本科生将参与这项研究。 因此，他们将获得知识和技能，为深造或进入科学/技术工作队伍做好准备。