RUI: Solid/Liquid Phase Diagrams of Aqueous Inorganic and Organic Substances of Upper Tropospheric Importance

RUI：对流层上层重要的水性无机和有机物质的固/液相图

• 批准号: 0442273
• 负责人: Keith Beyer
• 金额: --
• 依托单位: University of Wisconsin-La Crosse
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2004
• 资助国家: 美国
• 起止时间: 2004-07-01 至 2008-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0442273&HistoricalAwards=false
• 关键词: RUI; Solid; Liquid; Phase; Diagrams

This Research at Undergraduate Institutions (RUI) project extends upon successful past laboratory studies conducted by the P.I. investigating thermodynamic properties of aqueous and mixed-solute systems that emulate aerosol particles resident in the upper troposphere. Laboratory experiments will expand the range of thermochemical data - including equilibrium phase diagrams and solution heat capacities as a function of temperature and chemical composition - on a number of tropospherically relevant aqueous systems, using differential scanning calorimetry (DSC) and infrared (IR) spectroscopy. The P.I. will also verify theoretical model thermodynamics at low temperature by measuring enthalpies of fusion and solid-solid phase transitions of these systems, enabling identification of unknown solids in mixtures of several components at cold temperatures in the future. Undergraduate students will be extensively involved in laboratory experimental work and data analysis. With respect to broader impacts, this project will make a substantive contribution to current understanding of some important aerosol systems present in the global troposphere that influence radiative balance and cloud nucleation, while enhancing the education, professional training and research experience of a number of undergraduate students at a relatively small tertiary institution. The project results will provide the atmospheric science community with new data that may lead to more realistic and representative constraints on existing aerosol thermodynamic models.

该研究在本科院校（RUI）项目扩展了由PI进行的成功的实验室研究。研究模拟对流层上部气溶胶粒子的水和混合溶质系统的热力学性质。 实验室实验将扩大热化学数据的范围-包括平衡相图和溶液热容作为温度和化学成分的函数-在一些对流层相关的含水系统，使用差示扫描量热法（DSC）和红外（IR）光谱。 私家侦探还将通过测量这些系统的熔融和固-固相变的温度来验证低温下的理论模型热力学，从而能够在未来的低温下识别几种组分的混合物中的未知固体。 本科生将广泛参与实验室实验工作和数据分析。 在更广泛的影响方面，该项目将对目前对全球对流层中影响辐射平衡和云成核的一些重要气溶胶系统的了解作出实质性贡献，同时加强一个相对较小的高等院校的一些本科生的教育、专业培训和研究经验。 该项目的成果将为大气科学界提供新的数据，可能导致对现有气溶胶热力学模型的更现实和更有代表性的限制。