Application of Advanced Spectroscopic Techniques to the Study of Key Reactive Chemical Intermediates

先进光谱技术在关键活性化学中间体研究中的应用

• 批准号: 0511809
• 负责人: Terry Miller
• 金额: $ 62.34万
• 依托单位: Ohio State University Research Foundation -DO NOT USE
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2005
• 资助国家: 美国
• 起止时间: 2005-09-01 至 2009-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0511809&HistoricalAwards=false
• 关键词: Application; Advanced; Spectroscopic; Techniques; Study

In this award, funded by the Experimental Physical Chemistry Program of the Chemistry Division, Prof. Terry A. Miller of Ohio State University and his post-doctoral and graduate research students will investigate the spectroscopy of a series of alkoxy and peroxy radicals. In addition, they will carry out extensive experimental investigations of conical intersections in a small number of molecules. The goals of the first experiments are to provide diagnostic markers for radical molecules that are important in combustion and atmospheric chemistry, while the latter experiments will provide data that will help chemists understand the ways in which conical intersections influence chemical reactions.Besides the broader scientific impacts of the proposed studies, the young researchers working on these projects will acquire excellent training in physical chemistry - gaining invaluable experience in both sophisticated experimental and theoretical methods.

在该奖项中，由化学系实验物理化学项目资助，俄亥俄州立大学的Terry A. Miller教授及其博士后和研究生将研究一系列烷氧基和过氧自由基的光谱。 此外，他们还将对少量分子的圆锥形交叉点进行广泛的实验研究。 第一个实验的目标是为燃烧和大气化学中重要的自由基分子提供诊断标记，而后面的实验将提供数据，帮助化学家了解圆锥形交叉点影响化学反应的方式。除了拟议研究的更广泛的科学影响之外，从事这些项目的年轻研究人员还将获得物理化学方面的良好培训 - 在复杂的实验和实验中获得宝贵的经验。 理论方法。