The Spectroscopy of Chemical Intermediates and Other Transient Species
化学中间体和其他瞬态物质的光谱学
基本信息
- 批准号:9005963
- 负责人:
- 金额:$ 59.96万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Continuing grant
- 财政年份:1990
- 资助国家:美国
- 起止时间:1990-07-01 至 1994-06-30
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
Professor Miller is supported by the Experimental Physical Chemistry Program to investigate the spectroscopy of various transient chemical species. Such chemical intermediates as reactive atoms, free radicals, and molecular ions often play critical roles in reactions in combustion, solvation, synthetic processes, and the chemistry of the atmosphere. Spectroscopic identification and characterization is important both for monitoring these intermediates and for understanding their structures and interactions. Two facilities constructed under prior NSF support are used in this work. One facility, dedicated to the study of ionic clusters, uses laser-induced fluorescence to probe cluster structure and time-of-flight mass spectrometry to determine the number of atoms. The second apparatus prepares neutral radicals in a pulsed supersonic jet for ultra-high resolution pulsed laser spectroscopy designed to reveal details of rotational structure. Species under investigation range from small polyatomics to multi-ring aromatic radicals and include clusters containing ions or open-shell radicals.
米勒教授在实验物理化学计划的支持下研究各种瞬态化学物质的光谱。 活性原子、自由基和分子离子等化学中间体通常在燃烧、溶剂化、合成过程和大气化学反应中发挥关键作用。 光谱鉴定和表征对于监测这些中间体以及了解它们的结构和相互作用都很重要。 这项工作使用了在 NSF 先前支持下建造的两个设施。 一座致力于研究离子团簇的设施,使用激光诱导荧光来探测团簇结构,并使用飞行时间质谱法来确定原子数量。 第二台设备在脉冲超音速射流中制备中性自由基,用于超高分辨率脉冲激光光谱,旨在揭示旋转结构的细节。 正在研究的物种范围从小型多原子到多环芳族自由基,包括含有离子或开壳自由基的簇。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
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Terry Miller其他文献
Book Reviews: Behavior Change in the Human Services: An Introduction to Principles and Applications by Martin Sundel and Sandra S. Sundel. Exploring Personality: An Intellectual Odyssey by Russell L. Ackoff. The Ecologist: The Cosmic Covenant.
- DOI:
10.1023/a:1009519228623 - 发表时间:
2000-01-01 - 期刊:
- 影响因子:1.600
- 作者:
Anthea Hewitt;Dennis E. Finlayson;Terry Miller - 通讯作者:
Terry Miller
Strategies for hydrogen storage in a depleted sandstone reservoir from the San Joaquin Basin, California (USA) based on high-fidelity numerical simulations
基于高保真数值模拟的美国加利福尼亚州圣华金盆地枯竭砂岩储层储氢策略
- DOI:
10.1016/j.est.2024.112508 - 发表时间:
2024 - 期刊:
- 影响因子:9.4
- 作者:
Shaowen Mao;Mohamed Z. Mehana;Tianjia Huang;G. Moridis;Terry Miller;E. Guiltinan;Michael R. Gross - 通讯作者:
Michael R. Gross
The key to commercial-scale geological CO<sub>2</sub> sequestration: Displaced fluid management
- DOI:
10.1016/j.egypro.2011.02.373 - 发表时间:
2011-01-01 - 期刊:
- 影响因子:
- 作者:
Ronald C. Surdam;Zunsheng Jiao;Philip Stauffer;Terry Miller - 通讯作者:
Terry Miller
Terry Miller的其他文献
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{{ truncateString('Terry Miller', 18)}}的其他基金
Theoretical studies of spectroscopic and dynamic implications of large amplitude vibrations
大振幅振动的光谱和动力学影响的理论研究
- 批准号:
1213347 - 财政年份:2012
- 资助金额:
$ 59.96万 - 项目类别:
Continuing Grant
High Resolution Spectroscopy of Reactive Chemical Intermediates and Related Studies
反应性化学中间体的高分辨率光谱及相关研究
- 批准号:
1012094 - 财政年份:2010
- 资助金额:
$ 59.96万 - 项目类别:
Continuing Grant
Application of Advanced Spectroscopic Techniques to the Study of Key Reactive Chemical Intermediates
先进光谱技术在关键活性化学中间体研究中的应用
- 批准号:
0511809 - 财政年份:2005
- 资助金额:
$ 59.96万 - 项目类别:
Continuing Grant
Moderate and High Resolution Spectroscopy of Reactive Chemical Intermediates
反应性化学中间体的中高分辨率光谱
- 批准号:
0211281 - 财政年份:2002
- 资助金额:
$ 59.96万 - 项目类别:
Continuing Grant
Spectroscopic Investigations of Reactive Chemical Intermediates
反应性化学中间体的光谱研究
- 批准号:
9974404 - 财政年份:1999
- 资助金额:
$ 59.96万 - 项目类别:
Continuing grant
Spectroscopic Detection and Characterization of Chemical Intermediates
化学中间体的光谱检测和表征
- 批准号:
9320909 - 财政年份:1994
- 资助金额:
$ 59.96万 - 项目类别:
Continuing grant
Reduced one Carbon Biosynthetic Pathways of the Methanogen Methanosphaera stadtmanae
产甲烷菌 Methanosphaera stadtmanae 的还原碳生物合成途径
- 批准号:
9017471 - 财政年份:1991
- 资助金额:
$ 59.96万 - 项目类别:
Continuing Grant
Spectroscopic Studies of Clusters and Their Chemistry
团簇及其化学的光谱研究
- 批准号:
8803169 - 财政年份:1988
- 资助金额:
$ 59.96万 - 项目类别:
Continuing grant
The Spectroscopy of Chemical Intermediates and Other Transient Species
化学中间体和其他瞬态物质的光谱学
- 批准号:
8507537 - 财政年份:1985
- 资助金额:
$ 59.96万 - 项目类别:
Continuing grant
Gordon Research Conference on Plasma Chemistry, August 13-17, 1984, Tilton, New Hampshire
戈登等离子体化学研究会议,1984 年 8 月 13-17 日,新罕布什尔州蒂尔顿
- 批准号:
8405137 - 财政年份:1984
- 资助金额:
$ 59.96万 - 项目类别:
Standard Grant
相似国自然基金
Chinese Journal of Chemical Engineering
- 批准号:21224004
- 批准年份:2012
- 资助金额:20.0 万元
- 项目类别:专项基金项目
Chinese Journal of Chemical Engineering
- 批准号:21024805
- 批准年份:2010
- 资助金额:20.0 万元
- 项目类别:专项基金项目
相似海外基金
Quantifying Surface Chemical Intermediates and Interfacial Redox Processes via Combined Raman Spectroscopy and Scanning Electrochemical Microscopy
通过拉曼光谱和扫描电化学显微镜相结合量化表面化学中间体和界面氧化还原过程
- 批准号:
2004054 - 财政年份:2020
- 资助金额:
$ 59.96万 - 项目类别:
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Gas-phase spectroscopy of chemical intermediates produced in solution
溶液中产生的化学中间体的气相光谱
- 批准号:
20H00374 - 财政年份:2020
- 资助金额:
$ 59.96万 - 项目类别:
Grant-in-Aid for Scientific Research (A)
IDBR TYPE A: Definitive Chemical Analysis of Microbial Volatile Mixtures and Chemical Intermediates via Microwave Spectroscopy
IDBR A 型:通过微波光谱法对微生物挥发性混合物和化学中间体进行确定性化学分析
- 批准号:
1832846 - 财政年份:2017
- 资助金额:
$ 59.96万 - 项目类别:
Standard Grant
IDBR TYPE A: Definitive Chemical Analysis of Microbial Volatile Mixtures and Chemical Intermediates via Microwave Spectroscopy
IDBR A 型:通过微波光谱法对微生物挥发性混合物和化学中间体进行确定性化学分析
- 批准号:
1555781 - 财政年份:2016
- 资助金额:
$ 59.96万 - 项目类别:
Standard Grant
High Resolution Spectroscopy of Reactive Chemical Intermediates and Related Studies
反应性化学中间体的高分辨率光谱及相关研究
- 批准号:
1012094 - 财政年份:2010
- 资助金额:
$ 59.96万 - 项目类别:
Continuing Grant
Ion Cluster Spectroscopy for Chemical Intermediates of Nucleophilic Addition and Substitution Reactions
亲核加成和取代反应化学中间体的离子簇光谱
- 批准号:
21350016 - 财政年份:2009
- 资助金额:
$ 59.96万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
Moderate and High Resolution Spectroscopy of Reactive Chemical Intermediates
反应性化学中间体的中高分辨率光谱
- 批准号:
0211281 - 财政年份:2002
- 资助金额:
$ 59.96万 - 项目类别:
Continuing Grant
Intermediates leading to solid GaN, GaP, AIN and AIP. New synthetic methods for molecular oligomers under mild conditions. Spectroscopy and quantum chemical investigations.
产生固体 GaN、GaP、AIN 和 AIP 的中间体。
- 批准号:
5165325 - 财政年份:1999
- 资助金额:
$ 59.96万 - 项目类别:
Priority Programmes
The Spectroscopy of Chemical Intermediates and Other Transient Species
化学中间体和其他瞬态物质的光谱学
- 批准号:
8507537 - 财政年份:1985
- 资助金额:
$ 59.96万 - 项目类别:
Continuing grant
Characterization of Intermediates in Chemical and Photo- Chemical Reactions By Time-Resolved Raman Spectroscopy
通过时间分辨拉曼光谱表征化学和光化学反应中的中间体
- 批准号:
7903854 - 财政年份:1979
- 资助金额:
$ 59.96万 - 项目类别:
Continuing Grant