GOALI: Mechanism-Based Design of Catalysts for Olefin/Acrylate Copolymerization

目标：基于机理的烯烃/丙烯酸酯共聚催化剂设计

• 批准号: 0516950
• 负责人: Richard Jordan
• 金额: $ 44.1万
• 依托单位: University of Chicago
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2005
• 资助国家: 美国
• 起止时间: 2005-09-01 至 2008-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0516950&HistoricalAwards=false
• 关键词: GOALI; Mechanism; Based; Design; Catalysts

Richard Jordan, in the Department of Chemistry at the University of Chicago, and Brian Goodall, in the Catalysis Group at Rohm and Haas Company, are supported by the Inorganic, Bioinorganic and Organometallic Chemistry GOALI Program to develop catalytic methods to polymerize functionalized olefins. Efforts to unravel the mechanisms by which current catalysts are capable of inserting olefins and acrylates will serve to guide design features for new catalysts that will lead to the copolymerization of olefins and acrylate monomers. The mechanistic studies and catalyst design components will be based in Chicago with the synthesis and analysis of polymers and molecular modeling based in Rohm and Haas laboratories at Spring House.Polymers are one of the foundational materials of the modern technical world. This project will generate mechanistic information that will guide the design of new catalysts capable of overcoming the polar monomer problem and allow linking of olefin and acrylate monomers to form new copolymer products.

芝加哥大学化学系的Richard Jordan和Rohm and哈斯公司催化组的Brian Goodall得到了无机、生物无机和有机金属化学GOALI计划的支持，以开发聚合官能化烯烃的催化方法。 努力解开目前的催化剂能够插入烯烃和丙烯酸酯的机制将有助于指导新催化剂的设计特征，这将导致烯烃和丙烯酸酯单体的共聚。 机械研究和催化剂设计部分将在芝加哥进行，聚合物的合成和分析以及分子建模将在Spring House的Rohm和哈斯实验室进行。聚合物是现代技术世界的基础材料之一。该项目将产生机理信息，指导能够克服极性单体问题的新催化剂的设计，并允许烯烃和丙烯酸酯单体连接形成新的共聚物产品。