Unusual Bonding Mechanisms and Reactions in Clusters

簇中不寻常的键合机制和反应

• 批准号: 0518094
• 负责人: Michael Heaven
• 金额: $ 40.88万
• 依托单位: Emory University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2005
• 资助国家: 美国
• 起止时间: 2005-08-01 至 2008-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0518094&HistoricalAwards=false
• 关键词: Unusual; Bonding; Mechanisms; Reactions; Clusters

In this award, funded by the Experimental Physical Chemistry Program of the Chemistry Division, Prof. Michael C. Heaven of Emory University and his post-doctoral, undergraduate and graduate research students will investigate (1) unusual bonding mechanisms and (2) intra-cluster reactions via a variety of spectroscopic methods. The ultimate aim of the former studies is to develop a better understanding of some compounds that exhibit modes of bonding that are not well-characterized in terms of conventional models while that for the latter is to investigate the ability to prealign reactants. The results from these studies will help chemists to develop a deeper understanding of bonding that encompasses the traditional models of bonding as well as the unusual interactions that are one of the themes of the present study. Both research projects will provide the young researchers working on them with significant exposure to advanced experimental and theoretical methods.

在这个由化学系实验物理化学项目资助的奖项中，埃默里大学的Michael C.Heaven教授和他的博士后、本科生和研究生将通过各种光谱方法研究(1)不寻常的成键机制和(2)团簇内反应。前者的最终目的是为了更好地理解某些化合物的成键方式，而后者的最终目的是研究预对准反应物的能力。这些研究的结果将有助于化学家对成键有更深入的了解，包括传统的成键模型以及本研究的主题之一的不寻常的相互作用。这两个研究项目将为从事这项工作的年轻研究人员提供大量接触先进实验和理论方法的机会。