CAREER: New horizons in Coordination and Organometallic Chemistry of Azulene: A Combined Synthetic, Spectroscopic, Structural, Electrochemical, and Theoretical Investigation

职业:甘菊环配位和有机金属化学的新视野:综合合成、光谱、结构、电化学和理论研究

基本信息

项目摘要

This CAREER award by the Inorganic, Bioinorganic, and Organometallic Chemistry Program supports research and educational activities of Professor Mikhail Barybin of the Department of Chemistry, University of Kansas to develop rational strategies for incorporating the electronically unusual azulenic motif (a nonbenzenoid aromatic framework involving fused 5- and 7-membered carbon rings) into molecular and supramolecular hybrid metal/organic ensembles. This research undertakes a multifaceted approach to understand chemical reactivity and physical properties of a new class of azulenic derivatives, namely isocyanoazulenes, with the ultimate goal of designing ensembles suitable for developing unique azulene-based liquid crystals and one-dimensional charge transport materials. The development of metallomesogens (i.e., metal-containing liquid crystals) based on the 2,6-azulenic scaffold will deliver new and more cost-efficient platforms for fabricating azulene-containing liquid crystal devices, which are currently of substantial fundamental and commercial interest. The project will also provide new strategies for improving electron delocalization in the hybrid metal-organic systems relevant to applications in molecular electronics and nanotechnology. The integrated educational component of the project is aimed at promoting early involvement of undergraduate students in chemistry research. To this end, an innovative curriculum for freshmen level Honors Chemistry Laboratory that includes community outreach aspects will be developed and implemented. This course will provide opportunities for students to take greater control over the design and implementation of their laboratory investigations and will encourage undergraduates into chemistry research well before their senior year by fostering student engagement and both intellectual and technological skills.
这个由无机,生物无机和有机物化学计划颁发的职业奖支持堪萨斯大学化学系Mikhail Barybin教授的研究和教育活动,以开发将电子不寻常的azulenic基序(一种涉及稠合5-和7-元碳环的非苯型芳族框架)纳入分子和超分子混合金属/有机系综的合理策略。 本研究采用多方面的方法来了解一类新的azulenic衍生物(即isocyanoazulenes)的化学反应性和物理性质,最终目标是设计适合开发独特的azulene基液晶和一维电荷传输材料的合奏。 金属介晶的发展(即,含金属的液晶)将提供新的和更有成本效益的平台,用于制造目前具有实质性基础和商业利益的含甘菊环的液晶器件。 该项目还将为改善与分子电子学和纳米技术应用相关的混合金属-有机体系中的电子离域提供新的策略。 该项目的综合教育部分旨在促进本科生尽早参与化学研究。 为此,将制定和实施一项包括社区外展方面的新生级荣誉化学实验室创新课程。 本课程将为学生提供机会,以更好地控制他们的实验室调查的设计和实施,并将鼓励本科生进入化学研究以及在他们的大四之前,通过培养学生的参与和智力和技术技能。

项目成果

期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)

数据更新时间:{{ journalArticles.updateTime }}

{{ item.title }}
{{ item.translation_title }}
  • DOI:
    {{ item.doi }}
  • 发表时间:
    {{ item.publish_year }}
  • 期刊:
  • 影响因子:
    {{ item.factor }}
  • 作者:
    {{ item.authors }}
  • 通讯作者:
    {{ item.author }}

数据更新时间:{{ journalArticles.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ monograph.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ sciAawards.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ conferencePapers.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ patent.updateTime }}

Mikhail Barybin其他文献

Mikhail Barybin的其他文献

{{ item.title }}
{{ item.translation_title }}
  • DOI:
    {{ item.doi }}
  • 发表时间:
    {{ item.publish_year }}
  • 期刊:
  • 影响因子:
    {{ item.factor }}
  • 作者:
    {{ item.authors }}
  • 通讯作者:
    {{ item.author }}

{{ truncateString('Mikhail Barybin', 18)}}的其他基金

Design of oligozulene-based organometallics for probing new paradigms in charge delocalization, transport, and storage at the nanoscopic scale
设计基于低聚菊烯的有机金属化合物,用于探索纳米尺度电荷离域、传输和存储的新范例
  • 批准号:
    1808120
  • 财政年份:
    2018
  • 资助金额:
    $ 50万
  • 项目类别:
    Standard Grant
Azulene-bridged Organometallics: New Platforms for Charge Delocalization and Transport at the Nanoscale
甘菊桥有机金属化合物:纳米尺度电荷离域和传输的新平台
  • 批准号:
    1214102
  • 财政年份:
    2012
  • 资助金额:
    $ 50万
  • 项目类别:
    Standard Grant

相似海外基金

New Horizons in Quinonedimethide Chemistry
醌二甲基化学的新视野
  • 批准号:
    DP240100555
  • 财政年份:
    2024
  • 资助金额:
    $ 50万
  • 项目类别:
    Discovery Projects
AMPQuest - Journeying to new horizons in treating drug-resistant infections.
AMPQuest - 迈向治疗耐药感染的新视野。
  • 批准号:
    BB/Y514019/1
  • 财政年份:
    2024
  • 资助金额:
    $ 50万
  • 项目类别:
    Research Grant
Conference: New horizons in language science: large language models, language structure, and the neural basis of language
会议:语言科学的新视野:大语言模型、语言结构和语言的神经基础
  • 批准号:
    2418125
  • 财政年份:
    2024
  • 资助金额:
    $ 50万
  • 项目类别:
    Standard Grant
New Horizons in the Atomistic Simulation of Charge and Exciton Transport in Optoelectronic Materials
光电材料中电荷和激子输运原子模拟的新视野
  • 批准号:
    2868548
  • 财政年份:
    2023
  • 资助金额:
    $ 50万
  • 项目类别:
    Studentship
New horizons in Electrostatic Force Microscopy
静电力显微镜的新视野
  • 批准号:
    EP/X018024/1
  • 财政年份:
    2023
  • 资助金额:
    $ 50万
  • 项目类别:
    Research Grant
EPSRC New Horizons 2021: Engineering synthetic synapses between artificial and biological cells.
EPSRC New Horizo​​ns 2021:人工细胞和生物细胞之间的工程合成突触。
  • 批准号:
    EP/X018903/1
  • 财政年份:
    2023
  • 资助金额:
    $ 50万
  • 项目类别:
    Research Grant
New horizons in operator algebras: finite-dimensional approximations and quantized function theory
算子代数的新视野:有限维近似和量化函数理论
  • 批准号:
    RGPIN-2022-03600
  • 财政年份:
    2022
  • 资助金额:
    $ 50万
  • 项目类别:
    Discovery Grants Program - Individual
Scanning New Horizons: Entanglement, Holography & Gravity
扫描新视野:纠缠、全息术
  • 批准号:
    SAPIN-2019-00031
  • 财政年份:
    2022
  • 资助金额:
    $ 50万
  • 项目类别:
    Subatomic Physics Envelope - Individual
New models, new approaches, new horizons in corneal nerve regeneration
角膜神经再生的新模型、新方法、新视野
  • 批准号:
    10574591
  • 财政年份:
    2022
  • 资助金额:
    $ 50万
  • 项目类别:
New models, new approaches, new horizons in corneal nerve regeneration
角膜神经再生的新模型、新方法、新视野
  • 批准号:
    10334864
  • 财政年份:
    2022
  • 资助金额:
    $ 50万
  • 项目类别:
{{ showInfoDetail.title }}

作者:{{ showInfoDetail.author }}

知道了