Force Maps, Aging, and Elasticity in Random, Non-Equilibrium Solids

随机非平衡固体中的力图、老化和弹性

• 批准号: 0605839
• 负责人: Anthony Dinsmore
• 金额: $ 34.5万
• 依托单位: University of Massachusetts Amherst
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2006
• 资助国家: 美国
• 起止时间: 2006-08-01 至 2009-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0605839&HistoricalAwards=false
• 关键词: Force; Maps; Aging; Elasticity; Random

Technical Abstract:Optical microscopy will be used to measure structure, topology, forces and elastic constants inside disordered solids in three dimensions. The great scientific challenge of these materials is that they are both random and far from thermal equilibrium and thus not readily described by thermodynamics. The basic approach of this project is to measure the positions of particles in two or three dimensions, along with their thermal fluctuations or the distortions of their shape by contact forces. The particles used will range from micron-size neutrally buoyant colloidal spheres -- whose motions are thermal -- to 20-micrometers heavy droplets, which form static piles with zero effective temperature. Attractive interactions induced among the small particles lead to gelation and this process will also be studied in reverse. The data allow unusually explicit comparisons of forces, elastic constants, and material structure, which are essential to develop and test theoretical models. High-school, undergraduate, and graduate students participate in the research. The project also informs development of a course in soft matter physics, which will be shared with instructors at other institutions.Non-technical Abstract: Disordered solids are very common in everyday life, with examples including window glass, polymer gels, particle gels, and sand piles. Although the microscopic details of these examples differ tremendously -- molecules in one case and millimeter-sized sand grains in another -- there is increasing evidence that they are examples of a more general phenomenon known as "jamming". The goal of this project is to use advanced techniques of optical microscopy to measure structure, topology, forces, and elastic constants throughout these materials. One set of measurements focuses on the forces among droplets inside a concentrated emulsion, which serves as a useful model of a sandpile without static friction. A parallel set of measurements focuses on the formation and melting of random particle aggregates (gels). The results will contribute to a deep and broadly applicable understanding of elasticity and aging in disordered solids. A key component of this project is the participation of high-school, undergraduate, and graduate students, who will receive training in soft matter physics suitable for careers in industry, national labs, or academia.

技术摘要：光学显微镜将用于测量三维无序固体内部的结构、拓扑、力和弹性常数。这些材料的巨大科学挑战在于它们是随机的，远离热平衡，因此不容易用热力学描述。 该项目的基本方法是测量颗粒在二维或三维中的位置，沿着它们的热波动或它们的形状因接触力而变形。所用的颗粒将从微米大小的中性浮力胶体球（其运动是热的）到20微米重的液滴（其形成具有零有效温度的静态堆）。小颗粒之间诱导的吸引力相互作用导致凝胶化，这一过程也将反过来研究。这些数据允许对力、弹性常数和材料结构进行异常明确的比较，这对于开发和测试理论模型至关重要。高中生、本科生和研究生都参加了这项研究。该项目还为软物质物理学课程的开发提供了信息，该课程将与其他机构的教师分享。非技术摘要：无序固体在日常生活中非常常见，例如窗户玻璃，聚合物凝胶，颗粒凝胶和沙堆。尽管这些例子的微观细节差别很大-一个例子是分子，另一个例子是毫米大小的沙粒-但越来越多的证据表明，它们是一种更普遍的现象，即所谓的“堵塞”。 该项目的目标是使用先进的光学显微镜技术来测量这些材料的结构，拓扑结构，力和弹性常数。一组测量集中在浓缩乳液内的液滴之间的力，这是一个没有静摩擦的沙堆的有用模型。一组平行的测量集中在随机颗粒聚集体（凝胶）的形成和熔化。结果将有助于深入和广泛适用的理解弹性和无序固体老化。该项目的一个关键组成部分是高中，本科和研究生的参与，他们将接受适合工业，国家实验室或学术界职业的软物质物理学培训。