RUI: Fundamental Study of the Kinetics and Mechanism of the Reaction of Allyl Bromides at Indium Surfaces

RUI：铟表面烯丙基溴反应动力学和机理的基础研究

• 批准号: 0653311
• 负责人: Walter Bowyer
• 金额: $ 17.05万
• 依托单位: Hobart and William Smith Colleges
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2007
• 资助国家: 美国
• 起止时间: 2007-06-01 至 2011-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0653311&HistoricalAwards=false
• 关键词: RUI; Fundamental; Study; Kinetics; Mechanism

AbstractCHE-0653311Bowyer/Hobart and William SmithThis research project, carried out at a primarily undergraduate institution, examines the kinetics of the surface catalyzed indium allylation reaction. With the support of the Analytical and Surface Chemistry Program, Professor Bowyer and his undergraduate colleagues are investigating the reaction kinetics of the indium mediated allylation reaction carried out in aqueous solution. Using photomicrography to follow the heterogeneous reaction, direct information about the mechanism and rate constants for the C-C coupling reaction under "green" chemistry conditions is obtained. Undergraduate students are involved in all aspects of the research ranging from data collection and analysis to the presentation and publication of the results of the research. With the support of the Analytical and Surface Chemistry Program, Professor Bowyer and his undergraduate colleagues at Hobart and William Smith Colleges are examining the kinetics of the indium catalyzed carbon coupling reaction in aqueous media. This green chemistry process is likely to have significant impact in the fine chemicals and pharmaceutical industry. Using photomicrography, the heterogeneous reaction process is directly followed, and fundamental mechanistic and kinetic information obtained.

Bowyer/霍巴特和William Smith这一研究项目在一个主要的本科院校进行，研究了表面催化的铟烯丙基化反应的动力学。 在分析和表面化学项目的支持下，Bowyer教授和他的本科同事正在研究在水溶液中进行的铟介导的烯丙基化反应的反应动力学。 利用显微照相技术跟踪反应过程，获得了绿色化学条件下碳碳偶联反应的机理和速率常数的直接信息。 本科生参与研究的各个方面，从数据收集和分析到研究结果的展示和出版。在分析和表面化学项目的支持下，鲍耶教授和他在霍巴特和威廉史密斯学院的本科生同事正在研究铟催化的碳偶联反应在水介质中的动力学。 这种绿色化学过程可能在精细化学品和制药工业中产生重大影响。 使用显微照相，直接跟踪非均相反应过程，并获得基本的机理和动力学信息。