Conjugated Inorganic-Organic Materials: The Next Generation

无机-有机共轭材料：下一代

• 批准号: 0748982
• 负责人: John Protasiewicz
• 金额: $ 47.1万
• 依托单位: Case Western Reserve University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2007
• 资助国家: 美国
• 起止时间: 2007-12-15 至 2012-11-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0748982&HistoricalAwards=false
• 关键词: Conjugated; Inorganic; Organic; Materials; Next

This award in the Inorganic, Bioinorganic and Organometallic Chemistry Program supports research by Professor John D. Protasiewicz at Case-Western Reserve University to investigate the constituent carbenes (R2C) of conjugated polymers with heavier analogs (such as phosphinidenes, RP) to produce nearly isostructural conjugated materials that are electronically modulated (having E=C and E=E bonds versus C=C bonds). Specific goals include: 1. The development of new and better methodology for high yield synthesis of extended conjugated materials; 2. New monomers for constructing extended systems with greater conjugation and photoluminescent responses; and, 3) Discovery of new extended systems having interesting optical and electronic properties. Graduate and undergraduate students will receive education and mentoring in organic, inorganic, main group, polymer, and physical chemistry. The PI also mentors high school students in his laboratory, and serves as advisor to local ACS affiliates and student groups.

This award in the Inorganic, Bioinorganic and Organometallic Chemistry Program supports research by Professor John D. Protasiewicz at Case-Western Reserve University to investigate the constituent carbenes (R2C) of conjugated polymers with heavier analogs (such as phosphinidenes, RP) to produce nearly isostructural conjugated materials that are electronically modulated (having E=C and E=E bonds对C = C键）。 具体目标包括：1。开发新的和更好的方法，用于高产综合的扩展共轭材料； 2。用于构建具有更大结合和光致发反应的扩展系统的新单体； 3）发现具有有趣的光学和电子特性的新扩展系统。研究生和本科生将获得有机，无机，主要组，聚合物和物理化学的教育和指导。 PI还指导他的实验室中的高中生，并担任当地ACS分支机构和学生团体的顾问。