Conjugated Inorganic-Organic Materials: The Next Generation

无机-有机共轭材料：下一代

• 批准号: 0748982
• 负责人: John Protasiewicz
• 金额: $ 47.1万
• 依托单位: Case Western Reserve University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2007
• 资助国家: 美国
• 起止时间: 2007-12-15 至 2012-11-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0748982&HistoricalAwards=false
• 关键词: Conjugated; Inorganic; Organic; Materials; Next

This award in the Inorganic, Bioinorganic and Organometallic Chemistry Program supports research by Professor John D. Protasiewicz at Case-Western Reserve University to investigate the constituent carbenes (R2C) of conjugated polymers with heavier analogs (such as phosphinidenes, RP) to produce nearly isostructural conjugated materials that are electronically modulated (having E=C and E=E bonds versus C=C bonds). Specific goals include: 1. The development of new and better methodology for high yield synthesis of extended conjugated materials; 2. New monomers for constructing extended systems with greater conjugation and photoluminescent responses; and, 3) Discovery of new extended systems having interesting optical and electronic properties. Graduate and undergraduate students will receive education and mentoring in organic, inorganic, main group, polymer, and physical chemistry. The PI also mentors high school students in his laboratory, and serves as advisor to local ACS affiliates and student groups.

这个奖项在无机，生物无机和有机化学计划支持研究教授约翰D。Protasiewicz在凯斯西储大学研究共轭聚合物的组成卡宾（R2 C）与较重的类似物（如膦酰亚胺，RP），以产生几乎同构的共轭材料，电子调制（具有E=C和E=E键与C=C键）。 具体目标包括：1.发展新的更好的方法学，以高收率合成扩展共轭材料; 2.用于构建具有更大共轭和光致发光响应的扩展系统的新单体;以及3）发现具有感兴趣的光学和电子性质的新扩展系统。研究生和本科生将接受有机，无机，主组，聚合物和物理化学的教育和指导。PI还在他的实验室指导高中学生，并担任当地ACS附属机构和学生团体的顾问。