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New Frontiers in Synthesis of Main Group Systems with Novel Photophysical Properties

具有新颖光物理性质的主族体系合成新领域

基本信息

批准号：
1955845
负责人：
John Protasiewicz
金额：
$ 49万
依托单位：
Case Western Reserve University
依托单位国家：
美国
项目类别：
Standard Grant
财政年份：
2020
资助国家：
美国
起止时间：
2020-05-01 至 2024-04-30
项目状态：
已结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=1955845&HistoricalAwards=false
关键词：
New Frontiers Synthesis Main Group

项目摘要

The United States is in need of more economical means to manufacture highly efficient lighting and displays. Methods that can rely upon inexpensive and abundant elements and ones that minimize the formation of wasteful and toxic byproducts are especially attractive. To meet this need the Synthesis Program of the Chemistry Division of the National Science Foundation supports the research of Professor John D. Protasiewicz of the Case Western Reserve University into the preparation of low cost/lightweight/processable plastics and materials related to light emitting technology. Examples, include polymers, molecular electronics, light emitting diodes, photovoltaics, and flexible electronics. The students and postdocs trained and educated as part of this research program are needed as part of the country's highly skilled workforce in industry and education. In addition to the technical broader impacts related to advanced manufaturing, Professor Protasiewicz co-organizes and runs special orientation programs directed at raising awareness of mental health issues among graduate students and faculty. Main group systems with novel reactivity and bonding modes are examined to advance and create new paradigms in photophysical chemistry. Building on recently developed multiply-bonded organophosphorus chemistry dynamic carbene chemistry, electropolymerization, and fluorescence turn-on chemosensors are explored. Isolable carbenes are examined as control elements in dynamic photochemical systems. Luminescent and functional derivatives of 1,3-benzoxaphopsholes (BOPs) and 1,3-benzazaphopsholes (BAPs) are examined to create P,O- and P,N-chelated complexes to serve as robust functional materials for light emitting diode applications. New routes to materials containing photoactive BOPs and BAPs are developed, as well as new types of electropolymerization reactions to produce materials with electrochromism. The Professor Protasiewicz co-organizes and runs special orientation programs directed at raising awareness of mental health issues among graduate students and faculty.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

美国需要更经济的手段来制造高效照明和显示器。能够依赖廉价且丰富的元素以及最大限度地减少浪费和有毒副产品形成的方法尤其有吸引力。为了满足这一需求，美国国家科学基金会化学部的合成计划支持凯斯西储大学的 John D. Protasiewicz 教授的研究，以制备与发光技术相关的低成本/轻质/可加工塑料和材料。例子包括聚合物、分子电子学、发光二极管、光伏和柔性电子学。作为该研究计划的一部分，接受培训和教育的学生和博士后需要成为该国工业和教育领域高技能劳动力的一部分。除了与先进制造相关的更广泛的技术影响外，Protasiewicz 教授还共同组织并开展了专门的定向项目，旨在提高研究生和教师对心理健康问题的认识。研究具有新颖反应性和键合模式的主族系统，以推进和创造光物理化学的新范例。以最近开发的多重键有机磷化学为基础，探索了动态卡宾化学、电聚合和荧光开启化学传感器。可分离卡宾作为动态光化学系统中的控制元件进行检查。研究人员对 1,3-苯并氧杂环空洞 (BOP) 和 1,3-苯并氧杂环空洞 (BAP) 的发光和功能衍生物进行了研究，以创建 P,O- 和 P,N- 螯合络合物，作为发光二极管应用的强大功能材料。开发了含有光活性 BOP 和 BAP 的材料的新路线，以及生产电致变色材料的新型电聚合反应。 Protasiewicz 教授共同组织并开展了专门的定向计划，旨在提高研究生和教师对心理健康问题的认识。该奖项反映了 NSF 的法定使命，并通过使用基金会的智力价值和更广泛的影响审查标准进行评估，被认为值得支持。