Ultrafast Molecular Dynamics in Metal Complexes (C04)

金属配合物中的超快分子动力学 (C04)

• 批准号: 189482588
• 金额: --
• 依托单位: Arbeitsgruppe Clusterchemie
• 依托单位国家: 德国
• 项目类别: CRC/Transregios
• 财政年份: 2011
• 资助国家: 德国
• 起止时间: 2010-12-31 至 2021-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/189482588?language=en
• 关键词: Ultrafast; Molecular; Dynamics; Metal; Complexes

This 3MET project employs femtosecond time-resolved laser spectroscopies such as transient absorption in the UV/Vis, NIR, mid-IR, transient reflectivity, transient photofragmentation, and time resolved anisotropy. It investigates condensed and gas phase dynamics of ligand stabilized transition metal complexes. It fo-cusses on the influence of intermetallic cooperativity on photophysical and -chemical elementary processes. Together with inorganic synthesis and quantum-chemical calculations the employed techniques allow for systematic investigations, ranging from the isolated and the solvated system to the application-relevant solid state matrix.

该3 MET项目采用飞秒时间分辨激光光谱学，例如在UV/维斯、NIR、中红外、瞬态反射率、瞬态光致碎裂和时间分辨各向异性中的瞬态吸收。它研究了配体稳定的过渡金属配合物的凝聚态和气相动力学。重点讨论了金属间化合物协同效应对物理和化学基本过程的影响。连同无机合成和量子化学计算所采用的技术允许系统的调查，范围从孤立和溶剂化系统的应用相关的固态矩阵。