Novel molecular engineering and processing approaches for high-performance organic transistor devices: the role of polymer structure and morphology

高性能有机晶体管器件的新型分子工程和加工方法：聚合物结构和形态的作用

• 批准号: 0824188
• 负责人: Lisa Porter
• 金额: $ 50万
• 依托单位: Carnegie-Mellon University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2008
• 资助国家: 美国
• 起止时间: 2008-09-01 至 2012-02-29
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0824188&HistoricalAwards=false
• 关键词: Novel; molecular; engineering; processing; approaches

Research and development of organic semiconductors for electronic applications have shown intense growth in the last few years. Versatile attributes, such as solution processability and low cost, render these materials particularly attractive for applications such as electronic displays on flexible substrates, organic field effect transistors (OFETs) and large-area photovoltaics. However, carrier mobilities in organic semiconductors are much lower than their inorganic homologues. Evidence now indicates that carrier mobility in these systems depends on molecular structure and organization. Intellectual merit: Our objective is to achieve better understanding of structural ordering effects on carrier mobility in polymer-based electronic devices. We propose to focus on optimizing the performance of OFETs based on polymers using novel synthesis and processing techniques that will achieve both amorphous and highly crystalline polymer morphologies. Our approach will include correlations of materials structural changes and device architecture with device performance. While the device applications will be focused on OFETs, the conclusions will pertain to a wide range of conducting polymer technologies.Broader impacts: It is the aim in this project to train two graduate students and three undergraduate researchers in the area of structure-property-performance relationships needed for breakthrough technologies in electronic polymer-based devices. The students will have opportunities to interact with Plextronics, a local company and a technology leader in commercialization of organic light-emitting diodes and photovoltaics. The investigators will also collaborate with teachers in the Pittsburgh Public Schools (~60% minority students) on projects to experiment with conducting polymers.

在过去几年中，用于电子应用的有机半导体的研究和开发显示出强劲的增长。多用途的特性，如溶液可加工性和低成本，使这些材料对柔性衬底上的电子显示器、有机场效应晶体管（ofet）和大面积光伏等应用特别有吸引力。然而，有机半导体中的载流子迁移率远低于它们的无机同系物。现在有证据表明，这些体系中的载流子迁移率取决于分子结构和组织。智力优势：我们的目标是更好地理解结构排序对聚合物电子器件中载流子迁移率的影响。我们建议将重点放在优化基于聚合物的ofet的性能上，使用新的合成和加工技术，以实现非晶和高度结晶的聚合物形态。我们的方法将包括材料结构变化和器件结构与器件性能的相关性。虽然器件应用将集中在ofet上，但结论将适用于广泛的导电聚合物技术。更广泛的影响：该项目的目标是在电子聚合物基器件突破性技术所需的结构-性能-性能关系领域培养两名研究生和三名本科生研究人员。学生将有机会与pltronics互动，pltronics是一家本地公司，也是有机发光二极管和光伏商业化的技术领导者。研究人员还将与匹兹堡公立学校的教师（约60%是少数族裔学生）合作，进行导电聚合物的实验项目。