CRIF: MU Purchase of a Single Crystal X-Ray Diffractometer

CRIF：MU购买单晶X射线衍射仪

• 批准号: 0840456
• 负责人: Carol Fierke
• 金额: $ 30.02万
• 依托单位: Regents of the University of Michigan - Ann Arbor
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2009
• 资助国家: 美国
• 起止时间: 2009-08-01 至 2012-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0840456&HistoricalAwards=false
• 关键词: CRIF; MU; Purchase; Single; Crystal

This award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).With this award from the Chemistry Research Instrumentation and Facilities Multiuser Program (CRIF:MU), Professor Carol A. Fierke from the University of Michigan and colleagues Adam J. Matzger, John Montgomery, Vincent L. Pecoraro and Melanie S. Sanford will acquire a single crystal X-ray diffractometer with a strong copper source to obtain high-resolution structural information in diverse fields including synthetic organic chemistry, materials science and inorganic chemistry. This instrument will support education and research in complexes from metallacrowns producing soft materials; determination of absolute and relative stereochemistry of molecules important in catalytic reactions; in synthesis and characterization of biological properties of fluorinated proteins; in mechanistic studies of late metal complexes with high oxidation states; and in metal-organic frameworks.An X-ray diffractometer allows accurate and precise measurements of the full three dimensional structure of a molecule, including bond distances and angles, and provides accurate information about the spatial arrangement of a molecule relative to neighboring molecules. The studies described here will impact a number of areas, including chemistry, materials chemistry and biochemistry. This instrument will be an integral part of teaching as well as research.

This award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).With this award from the Chemistry Research Instrumentation and Facilities Multiuser Program (CRIF:MU), Professor Carol A. Fierke from the University of Michigan and colleagues Adam J. Matzger, John Montgomery, Vincent L. Pecoraro and Melanie S. Sanford will acquire a single crystal X-ray diffractometer with在包括合成有机化学，材料科学和无机化学的不同领域中获得高分辨率结构信息的强大铜来源。该仪器将支持产生软材料的冶金基综合体的教育和研究；确定在催化反应中重要的分子的绝对和相对立体化学；在氟化蛋白的生物学特性的合成和表征中；在具有高氧化态的后期金属复合物的机械研究中；在金属有机框架中。X射线衍射仪可以准确，精确地测量分子的整个三维结构，包括键距和角度，并提供有关分子相对于相邻分子的空间排列的准确信息。此处描述的研究将影响许多领域，包括化学，材料化学和生物化学。该工具将是教学和研究的组成部分。