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Electrochemical Oxidation and Sensing/Molecular Electronics Applications of Chemically- and Electrochemically-Synthesized Metal Nanostructures

Electrochemical Oxidation and Sensing/Molecular Electronics Applications of Chemically- and Electrochemically-Synthesized Metal Nanostructures
化学和电化学合成金属纳米结构的电化学氧化和传感/分子电子学应用
批准号:
0848883
负责人:
Francis Zamborini
金额:
$33.0万
依托单位国家:
美国
项目类别:
Continuing Grant
财政年份:
2009
资助国家:
美国
项目状态:
已结题
起止时间:
2009-07-01 至 2013-02-28

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中文摘要
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英文摘要
Professor Francis P. Zamborini of the University of Louisville is supported by the Analytical and Surface Chemistry Program in the Division of Chemistry to study the electrochemical reactivity and oxidation potential of silver and gold nanostructures as a function of size, shape, and surface chemistry. A second thrust of this supported research is to electrochemically synthesize Silver nanowires for sensing and molecular electronics applications. The proposed nanostructures will be characterized by spectroscopic, electrochemical and microscopic techniques. This research will lead to a better understanding of the effect of the size and shape of chemically and electrochemically synthesized nanostructures on the oxidation potential and the mechanisms of electron transfer at these nanoscale dimensions, which will push the field forward towards technological applications in miniaturized electronics, chemical sensing, and catalysis. Graduate and undergraduate students will participate in all aspects of the proposed research, and high school students will participate through outreach activities.
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Electrochemical Stability and Reactivity of Atomically Precise Single Metal and Alloy Clusters
Unique Electrochemistry and Optical Properties of Metal Nanoparticle Assemblies
Exploring the Unique Electrochemical Reactivity of Metallic Nanoparticles Less Than 4 nm in Diameter
Seed-Mediated Growth of Gold Nanorods Directly on Surfaces: Growth Mechanism, Functionalization, and Electronic Properties
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