Tailoring Hydrogen Storage Performance by Novel Mg-Catalyst Nano-Architectures

通过新型镁催化剂纳米结构定制储氢性能

• 批准号: 0853130
• 负责人: Yiping Zhao
• 金额: --
• 依托单位: University of Georgia Research Foundation Inc
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2009
• 资助国家: 美国
• 起止时间: 2009-08-15 至 2011-01-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0853130&HistoricalAwards=false
• 关键词: Tailoring; Hydrogen; Storage; Performance; Novel

0853130ZhaoIntellectual Merits: Hydrogen storage is the bottleneck for using hydrogen energy in on-board vehicle applications. In the pursuit of metal hydrides as solid state hydrogen storage media, magnesium hydride is considered to be a good candidate because of its lightweight, low cost, and high theoretical hydrogen storage capacity of 7.6 wt.%. Unfortunately, its high thermodynamic stability and sluggish reaction kinetics limit its practical applications. By tailoring the structural properties of nanomaterials, the thermodynamics and kinetics of hydrogen adsorption can be designed to satisfy the future hydrogen storage requirements. A fundamental understanding of hydrogen-nanostructure interactions also depends largely on the ability to fabricate nanostructures with the desired structural properties. In this proposal, the main goal is to use a novel nanofabrication technique, glancing angle deposition (GLAD), to design and produce novel Mg-catalyst nano-architectures with different topography, structure, and composition. This fabrication technique provides one with a vehicle to investigate the following important questions for hydrogen storage applications: (1) How would different nanoscale structures change the hydrogen storage behavior? (2) Would nanoscale catalysts, incorporated into nanostructured hydrogen storage materials in different forms, greatly enhance the storage behavior? Using this nanofabrication technique, the PI proposes to fabricate metal hydride nanostructures with different topographic structures to investigate the hydrogen storage ability and sorption performance. The hydrogen sorption performances of the nanostructures will be further improved by depositing different catalysts with different sizes and geometric forms. Broader Impacts: The success of this project will generate the following benefits: (1) It provides a generic methodology to fabricate well-designed metal hydride nanostructures or multilayered nanostructures. Therefore, the metal hydride materials that can be tailored into nanostructures are not limited to the proposed materials. (2) With the systematically designed metal hydride nanostructures and advanced characterization techniques, one can study at a fundamental level how hydrogen interacts with well-defined metal hydride nanostructures. (3) Optimal structures and conditions for fabricating the best metal hydride nanostructures for highly efficient hydrogen storage could be found. The lab-based nanotechnology course module that the PI will create will allow undergraduate and high school students to obtain provide hands-on experience on nanofabrication.

0853130 Zhao智力优势：氢存储是车载应用中使用氢能的瓶颈。在金属氢化物作为固态储氢介质的研究中，氢化镁被认为是一个很好的候选者，因为它重量轻，成本低，理论储氢容量高（7.6wt.%）。然而，它的高热力学稳定性和缓慢的反应动力学限制了它的实际应用。通过调整纳米材料的结构特性，可以设计氢吸附的热力学和动力学，以满足未来的储氢需求。对氢-纳米结构相互作用的基本理解也在很大程度上取决于制造具有所需结构特性的纳米结构的能力。在这项提案中，主要目标是使用一种新的纳米纤维技术，掠射角沉积（GLAD），设计和生产新的镁催化剂纳米结构与不同的地形，结构和组成。这种制备技术提供了一种研究储氢应用中以下重要问题的工具：（1）不同的纳米结构如何改变储氢行为？(2)将纳米催化剂以不同形式掺入纳米结构储氢材料中，是否会大大提高储氢性能？利用这种纳米纤维技术，PI提出制造具有不同形貌结构的金属氢化物纳米结构，以研究储氢能力和吸附性能。通过沉积不同尺寸和几何形状的催化剂，纳米结构的吸氢性能将进一步提高。更广泛的影响：该项目的成功将产生以下好处：（1）它提供了一种通用的方法来制备设计良好的金属氢化物纳米结构或多层纳米结构。因此，可以定制成纳米结构的金属氢化物材料不限于所提出的材料。(2)通过系统设计的金属氢化物纳米结构和先进的表征技术，人们可以在基础水平上研究氢如何与定义明确的金属氢化物纳米结构相互作用。(3)可以找到最佳的结构和条件，以制造最好的金属氢化物纳米结构，用于高效储氢。PI将创建基于实验室的纳米技术课程模块，将允许本科生和高中生获得纳米材料的实践经验。