Structural Evolution of Porous Coordination Polymers upon Chemical Exposure

化学暴露后多孔配位聚合物的结构演变

• 批准号: 0907369
• 负责人: Adam Matzger
• 金额: $ 51万
• 依托单位: Regents of the University of Michigan - Ann Arbor
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2009
• 资助国家: 美国
• 起止时间: 2009-06-15 至 2013-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0907369&HistoricalAwards=false
• 关键词: Structural; Evolution; Porous; Coordination; Polymers

TECHNICAL SUMMARY:The over-arching goal of this research is to develop a detailed, molecular level understanding of an emerging class of ultrahigh performance sorbents named Microporous Coordination Polymers (MCPs). MCP sorbent performance derives from their high fractional volume (porosity) of tiny, nanometer-sized pores resulting in exceedingly high specific surface areas. An understanding of how these materials can adsorb such enormous amounts of gases and the chemical/physical basis for selective uptake are the major thrusts of the proposed research. In particular, the fundamental role of pore size, pore architecture, and pore interconnectedness will be observed for the first time during the actual processes of gas adsorption and solvent removal. Enabling this unique viewpoint is the first use in MCPs of positron annihilation lifetime spectroscopy, an antimatter probe of porous materials recently developed to characterize microporous thin film dielectric insulators in microelectronic devices. Adoption of this technique has the potential to transform how researchers probe porosity in sorbents. Only by understanding how changes on the microscale and nanoscale exert an effect on apparent porosity can the best modes of exploiting existing MCPs be realized. Ultimately these results will be of practical use to guide the synthesis of new materials. MCP?s are expected to find broad application in energy research (gas storage) and environmental research (gas purification) and since MCPs are now being commercialized they are at the point where direct impact on society can and will be felt.NON-TECHNICAL SUMMARYThis research brings together chemists and physicists in an effort to transform the study of ultrahigh performance sorbents?the nanomaterials that are themselves transforming the field of chemical separations. This unique collaboration seeks to use powerful antimatter probe techniques recently developed to study newly engineered porous insulators in microchips to provide unprecedented structural characterization. These highly porous sorbents are expected to find broad application in alternative energy (gas storage) and industrial processes (gas purification) and since they are now beginning to be commercialized they are at the point where direct impact on society will be felt. The impact of this research is totally dependent on the successful interaction of chemists and physicists. Graduate and undergraduate students will cross discipline boundaries to learn in a broadly diverse and collaborative environment involving frequent interaction with industry. For these reasons the potential for obtaining transformative research results is high. However, this will only be possible if the properties of the materials are sufficiently well understood to allow widespread deployment in new more efficient processes. It is clear that sorbent technology has not yet achieved this point, but the proposed research will do much to enable reaching this goal.

技术摘要：本研究的主要目标是对一类新兴的具有生物学性能的吸附剂微孔配位聚合物（MCP）进行详细的分子水平的了解。MCP吸附剂的性能源自其微小的纳米尺寸孔的高分数体积（孔隙率），从而导致极高的比表面积。了解这些材料如何吸附如此大量的气体以及选择性吸收的化学/物理基础是拟议研究的主要目标。 特别是，在气体吸附和溶剂去除的实际过程中，将首次观察到孔径，孔结构和孔互连性的基本作用。使这一独特的观点是第一次使用在MCP的正电子湮没寿命谱，反物质探针的多孔材料最近开发的微电子器件中的微孔薄膜介电绝缘体的特征。采用这种技术有可能改变研究人员探测吸附剂孔隙率的方式。只有了解微尺度和纳米尺度上的变化如何对显气孔率产生影响，才能实现利用现有MCP的最佳模式。这些结果最终将对指导新材料的合成具有实际意义。MCP？的预计将找到广泛的应用在能源研究（气体储存）和环境研究（气体净化），因为MCP现在正在商业化，他们在那里对社会的直接影响，可以和将被认为是。非技术总结这项研究汇集了化学家和物理学家在努力改变的研究性能吸附剂？纳米材料本身正在改变化学分离领域。这项独特的合作旨在使用最近开发的强大的反物质探针技术来研究微芯片中新设计的多孔绝缘体，以提供前所未有的结构表征。 这些高度多孔的吸附剂预计将在替代能源（气体储存）和工业过程（气体净化）中得到广泛应用，并且由于它们现在开始商业化，因此它们将对社会产生直接影响。这项研究的影响完全取决于化学家和物理学家的成功互动。 研究生和本科生将跨越学科界限，在广泛多样的协作环境中学习，涉及与行业的频繁互动。 由于这些原因，获得变革性研究成果的潜力很大。 然而，只有充分了解材料的特性，才有可能在新的更有效的工艺中广泛部署。很明显，吸附剂技术还没有达到这一点，但拟议的研究将大大有助于实现这一目标。