Challenging Problems in Synthetic Chemistry

合成化学中的挑战性问题

• 批准号: 0956635
• 负责人: Karl Christe
• 金额: $ 54万
• 依托单位: University of Southern California
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2010
• 资助国家: 美国
• 起止时间: 2010-03-01 至 2013-02-28
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0956635&HistoricalAwards=false
• 关键词: Challenging; Problems; Synthetic; Chemistry

This award in the Chemical Synthesis (SYN) program supports work by Professor Karl Christe at the University of Southern California in Los Angeles to carry out fundamental studies on challenging problems in synthetic chemistry. Experimental efforts will be carried out in the following areas: (i) fluorine chemistry at the limits of oxidation and coordination; (ii) synthesis of novel cyano compounds for use as electrophilic cyanating agents and energetic fuels; and (iii) synthesis of new energetic fluorine substituted nitramines.The proposed activities will have a major impact on science and technology and result in important contributions to fields such as more efficient and greener energetic materials and synthesis at the limits of oxidation and coordination.

化学合成（SYN）计划中的这一奖项支持洛杉矶南加州大学的Karl Christe教授对合成化学中具有挑战性的问题进行基础研究。 将在下列领域进行实验工作：（一）氧化和配位极限的氟化学;（二）合成用作亲电氰化剂和高能燃料的新型氰基化合物;以及（iii）合成新的高能氟取代的硝胺。拟议的活动将对科学和技术产生重大影响，并对提高效率等领域作出重要贡献。以及在氧化和配位极限下的绿色含能材料和合成。