Collaborative Research: Infra-red Control of Electron Transfer Mechanisms

点击翻译按钮获取中文摘要

In this collaborative project supported by the Chemical Structure, Dynamics and Mechanisms Program of the Division of Chemistry, Professor David N. Beratan of Duke University and Professor Igor Rubtsov of Tulane University willdevelop methods to control electron transfer reactions, and to develop approaches to manipulate the strength of the electronic communication between molecules that influences the rate of electron transfer. The Beratan group will employ quantum and statistical mechanical theories to design, analyze and interpret inelastic electron-transfer kinetics in molecules with bridge-localized vibrational modes. The goal is to develop interpretive and predictive descriptions of intramolecular inelastic electron-tunneling in a variety of molecules containing an electron donor, a rigid bridge, and an electron acceptor. The Rubtsov group at Tulane will develop ultrafast laser and multi-dimensional infrared spectroscopic methods to examine analogies between the double slit electron transmission experiment and the molecular electron-transfer problem. This work will a broad impact in developing intuition that may lead to applications in optical communication and solar energy harvesting. Professors Beratan and Rubtsov are promoting science education by providing summer research opportunities to economically disadvantaged and historically underrepresented groups. A new course cluster for first-year students is under development to examine the fundamental philosophical foundations of science.