GOALI: Structure-Property Systematics in Novel Chalcogenide glasses with Modified Networks

GOALI：具有改进网络的新型硫属化物玻璃的结构-性能系统学

• 批准号: 1104869
• 负责人: Sabyasachi Sen
• 金额: $ 68.64万
• 依托单位: University of California-Davis
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2011
• 资助国家: 美国
• 起止时间: 2011-09-01 至 2016-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1104869&HistoricalAwards=false
• 关键词: GOALI; Structure; Property; Systematics; Novel

NON-TECHNICAL DESCRIPTION: Glassy materials such as sulfides, selenides and tellurides (i.e. chalcogenides) of Ge, As, Sb and P have found wide-ranging applications in the areas of photonics, telecommunication, memory storage, alternative energy resources and environmental remote sensing. The atomic structures of these materials are typically characterized by a network of covalently bonded atoms and structure-property relationships in these network chalcogenide glasses have been studied in detail. The physical and chemical characteristics of these networks can be substantially modified upon incorporation of elements such as Ba and Ga. Little, if any, is known about the unique properties of these new materials - they could result in transformative and wide-ranging technological applications. This research project brings together investigators with complementary expertise and common interests from UC Davis and Corning Incorporated (the world's foremost innovator and commercial developer of cutting-edge glass technology) to investigate the fundamental structure-property relationships in these novel chalcogenide materials. This project will finally enable the formulation of predictive models necessary for the optimization of these materials towards improved functionalities for potential commercialization. Students in this research project are learning to investigate problems in the realm of "basic science" that underlies industrial applications. The project is preparing students with powerful experimental skills and research experience in both academic and industrial settings that will open many opportunities for their careers. This project coordinates with the underrepresented minority-serving and other outreach programs at UC Davis to attract and recruit underrepresented graduate students and to increase the awareness of students in the science and technology of glassy materials. TECHNICAL DETAILS: This project entails studying the structure-property relationships and developing an atomic scale understanding of the structural mechanisms of transport and relaxation near the glass transition in novel modified and compensated network ternary and quaternary chalcogenide bulk glasses, fibers and supercooled liquids in the Ba-Ga-Ge-Se system. Accomplishing this goal involves application of a powerful combination of state-of-the-art techniques of physical property measurement and structural and dynamical characterization including nuclear magnetic resonance (NMR), Raman, optical absorption and fluorescence spectroscopy, high-energy X-ray diffraction and reverse Monte Carlo simulation. The results are being combined to develop predictive models, linking the atomic structure and dynamics with macroscopic physical properties that are crucial for compositional optimization of these materials for a wide range of technological applications. One example is exploring potential applications in photonics where these materials serve as efficient rare earth hosts with low phonon energy and high quantum efficiency. The interdisciplinary nature of this project impacts materials science and engineering, solid-state chemistry and physics and incorporates significant training of graduate students in state-of-the-art spectroscopic, diffraction and simulation techniques. The equipment and expertise at UC Davis, Corning Inc., National High Magnetic Field laboratory and Argonne National Laboratory provide students with a variety of modern research tools and a supportive structure for learning to use them. It continues to foster our longstanding collaborations with scientists in industry, academia and national laboratories and enriches the graduate education and training experience through numerous scientific dialogue and interactions between the collaborating scientists and participating students.FUNDING: This National Science Foundation project is co-funded by the Engineering Directorate and the Mathematical and Physical Sciences Directorate.

非技术描述：Ge、As、Sb和P的硫化物、硒化物和碲化物（即硫属化物）等玻璃材料在光子学、电信、存储器存储、替代能源和环境遥感等领域有着广泛的应用。这些材料的原子结构的典型特征是由共价键合的原子的网络和这些网络硫族化物玻璃中的结构-性能关系已被详细研究。 这些网络的物理和化学特性可以在掺入元素如Ba和Ga后得到显著改变。 人们对这些新材料的独特性能知之甚少--它们可能导致变革性和广泛的技术应用。 该研究项目汇集了来自加州大学戴维斯分校和康宁公司（世界上最重要的创新者和尖端玻璃技术的商业开发商）的具有互补专业知识和共同兴趣的研究人员，以研究这些新型硫属化物材料的基本结构-性能关系。 该项目最终将能够制定必要的预测模型，以优化这些材料，提高潜在商业化的功能。 这个研究项目的学生正在学习研究工业应用基础的“基础科学”领域的问题。 该项目正在为学生提供强大的实验技能和学术和工业环境中的研究经验，这将为他们的职业生涯提供许多机会。 该项目与加州大学戴维斯分校代表性不足的少数民族服务和其他推广计划相协调，以吸引和招募代表性不足的研究生，并提高学生对玻璃材料科学和技术的认识。 技术规格：该项目需要研究结构-性能关系，并在Ba-Ga-Ge-Se系统中对新型改性和补偿网络三元和四元硫族化物大块玻璃、纤维和过冷液体中玻璃化转变附近的传输和弛豫的结构机制进行原子尺度的理解。 实现这一目标涉及应用物理性质测量和结构及动力学表征的最新技术的强大组合，包括核磁共振（NMR）、拉曼、光吸收和荧光光谱、高能X射线衍射和反向蒙特卡罗模拟。这些结果正在被结合起来开发预测模型，将原子结构和动力学与宏观物理性质联系起来，这些物理性质对于这些材料的成分优化至关重要，适用于广泛的技术应用。一个例子是探索光子学中的潜在应用，其中这些材料作为具有低声子能量和高量子效率的有效稀土基质。 该项目的跨学科性质影响材料科学与工程，固态化学和物理，并结合了研究生在最先进的光谱，衍射和模拟技术的重要培训。 加州大学戴维斯分校的设备和专业知识，康宁公司，国家高磁场实验室和阿贡国家实验室为学生提供各种现代研究工具和学习使用它们的支持结构。它继续促进我们与工业界，学术界和国家实验室的科学家的长期合作，并通过合作科学家和参与学生之间的众多科学对话和互动丰富研究生教育和培训经验。资金：这个国家科学基金会项目由工程局和数学和物理科学局共同资助。