Synthesis of Polynuclear Transition Metal - Heavy Main Group Metal Carbonyl Complexes for Use as Next-Generation Multimetallic Heterogeneous Nano-Catalysts

用作下一代多金属多相纳米催化剂的多核过渡金属-重主族金属羰基配合物的合成

基本信息

项目摘要

In this project funded by the Chemical Synthesis Program of the Chemistry Division, Professor Richard D. Adams of the Department of Chemistry and Biochemistry at the University of South Carolina will continue to develop new procedures for the synthesis of multimetallic mixed-metal cluster complexes containing combinations of precious transition metals, e.g. ruthenium, rhodium, iridium and platinum with heavy main group metals, such as tin, antimony and bismuth. These new mixed-metal cluster complexes will be converted into bi- and multimetallic nanoparticles on supports to be used as new next-generation heterogeneous nanocatalysts for the selective hydrogenation of unsaturated hydrocarbons and the ammoxidation and partial oxidation of hydrocarbons. Emphasis will be placed on combinations of metals that can function cooperatively to perform difficult organic transformations and reactions with high selectivity. The conversion of these complexes into supported multimetallic nanoparticles will allow access to a new generation of multimetallic nanoclusters for applications in catalytic transformations and reactions of hydrocarbons. The broader impacts involve training of graduate and undergraduate students in research and to provide the experience required for them to compete in the highly technological professional environment of the U. S. chemical industry. They will learn to formulate and perform useful and intellectually challenging research and to solve chemical problems. The research experience will require both teamwork and independence, and will stimulate motivation, creativity and leadership. Students will be trained in the synthesis and characterization of organometallic compounds and heterogeneous catalysts. The project includes national and international collaborations that will broaden the education and experience of the students. The proposed heterogeneous multimetallic nanocatalysts may have an impact on areas that rely on the efficient organic transformations within pharmaceutical, chemical, and agricultural industries.
本研究由化学系化学合成计划资助,由美国加州大学伯克利分校化学系教授Richard D.南卡罗来纳州大学化学和生物化学系的亚当斯将继续开发合成多金属混合金属簇合物的新方法,该簇合物含有贵过渡金属如钌、铑、铱和铂与重主族金属如锡、锑和铋的组合。这些新的混合金属簇合物将被转化为双金属和多金属纳米粒子的支持,被用作新的下一代非均相纳米催化剂的选择性加氢的不饱和烃和氨氧化和烃的部分氧化。 重点将放在金属的组合,可以协同作用,以执行高选择性的困难的有机转化和反应。将这些配合物转化为负载型多金属纳米颗粒将允许获得新一代的多金属纳米团簇,用于烃的催化转化和反应。更广泛的影响包括研究生和本科生的研究培训,并为他们提供在美国高科技专业环境中竞争所需的经验。S.化工专业化他们将学习制定和执行有用的和智力上具有挑战性的研究,并解决化学问题。 研究经验将需要团队合作和独立性,并将激发动力,创造力和领导力。 学生将接受有机金属化合物和多相催化剂的合成和表征方面的培训。该项目包括国家和国际合作,将扩大学生的教育和经验。所提出的多相多金属纳米催化剂可能会对依赖于制药,化学和农业工业中的有效有机转化的领域产生影响。

项目成果

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Richard Adams其他文献

Hamsters and Gerbils: Advantages and Disadvantages as Models in Toxicity Testing
仓鼠和沙鼠:作为毒性测试模型的优点和缺点
  • DOI:
    10.3109/10915818509014500
  • 发表时间:
    1985
  • 期刊:
  • 影响因子:
    2.2
  • 作者:
    F. Homburger;C. V. Dongen;Richard Adams;E. Soto
  • 通讯作者:
    E. Soto
Session 4: What should we do for poor responders after chemoradiotherapy: bad biology or should the fight go on?
第四节:对于放化疗后反应不佳的患者我们应该做什么:生物学不良还是应该继续战斗?
  • DOI:
    10.1111/codi.14088
  • 发表时间:
    2018
  • 期刊:
  • 影响因子:
    3.4
  • 作者:
    J. Bhoday;B. Glimelius;Diana Tait;R. Glynne;Richard Adams;Gina Brown;Gina Brown
  • 通讯作者:
    Gina Brown
1116 PRIME-RT: Durvalumab with extended neoadjuvant regimens in locally advanced rectal cancer (LARC): a randomised phase II trial
1116 PRIME - RT:度伐利尤单抗联合扩展新辅助方案用于局部晚期直肠癌(LARC):一项随机Ⅱ期试验
  • DOI:
    10.1016/s0167-8140(25)00295-6
  • 发表时间:
    2025-05-01
  • 期刊:
  • 影响因子:
    5.300
  • 作者:
    Campbell S. Roxburgh;Catherine R. Hanna;Mark P. Saunders;Claire Arthur;Leslie M. Samuel;Lucy Wells;Rebecca Muirhead;Nicholas J. MacLeod;Janet S. Graham;Lynsey Devlin;Joanne Edwards;Lily V. Hillson;Ross K. McMahon;Ashley K. McCulloch;Lucy Paterson;Caroline Kelly;Liz-Anne Lewsley;Nicola Walker;Richard Adams;Sean M. O'Cathail
  • 通讯作者:
    Sean M. O'Cathail
Leptomeningeal carcinomatosis in advanced esophageal adenocarcinoma: A case report on presentation and diagnosis
  • DOI:
    10.1016/j.ijscr.2024.110708
  • 发表时间:
    2025-01-01
  • 期刊:
  • 影响因子:
  • 作者:
    Nathaniel Grabill;Mena Louis;Richard Adams;Claudia Gherasim;Sumi So;Timothy Stevens
  • 通讯作者:
    Timothy Stevens
2186 ARISTOTLE: Mature results of a phase 3 trial evaluating the addition of irinotecan to capecitabine chemoradiation in locally advanced rectal cancer
2186 亚里士多德研究:一项关于在局部晚期直肠癌中,在卡培他滨放化疗基础上加用伊立替康的3期试验的成熟结果
  • DOI:
    10.1016/s0167-8140(25)00901-6
  • 发表时间:
    2025-05-01
  • 期刊:
  • 影响因子:
    5.300
  • 作者:
    David Sebag-Montefiore;Leslie Samuel;Simon Gollins;Robert Glynne-Jones;Robert Harte;Nicholas West;Philip Quirke;Arthur Sun Myint;Simon Bach;Stephen Falk;Philip Parsons;Amandeep Dhadda;Vivek Misra;Gina Brown;Mark Harrison;Laura White;Marian Duggan;Rubina Begum;Elizabeth Chang;Rukan Musleh;Richard Adams
  • 通讯作者:
    Richard Adams

Richard Adams的其他文献

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{{ truncateString('Richard Adams', 18)}}的其他基金

Activation of Carbon-Hydrogen Bonds at Multinuclear Metal Sites
多核金属位点碳氢键的活化
  • 批准号:
    1764192
  • 财政年份:
    2018
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Standard Grant
Studies of the Activation and Functionalization of Hydrocarbons at Multinuclear Metal Sites in Transition Metal-Gold Complexes
过渡金属-金配合物中多核金属位点碳氢化合物的活化和功能化研究
  • 批准号:
    1464596
  • 财政年份:
    2015
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Continuing Grant
Drosophila germ-band extension as a model for understanding the integration of cell intrinsic and extrinsic forces during animal morphogenesis
果蝇种带延伸作为了解动物形态发生过程中细胞内在和外在力量整合的模型
  • 批准号:
    BB/J010278/1
  • 财政年份:
    2012
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Research Grant
The distribution of innovation activity across UK industry
英国工业界创新活动的分布
  • 批准号:
    ES/H031839/1
  • 财政年份:
    2009
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Fellowship
Unsaturated Heterometallic Cluster Complexes for Hydrogen Activation and Catalytic Hydrogenations
用于氢活化和催化加氢的不饱和异金属簇配合物
  • 批准号:
    0743190
  • 财政年份:
    2008
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Continuing Grant
Quantifying cell behaviour in morphogenesis
量化形态发生中的细胞行为
  • 批准号:
    EP/F058586/1
  • 财政年份:
    2008
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Research Grant
Sulfides and Disulfides of Di- and Polymetallic Carbonyl Complexes: Precursors to Nano-Catalysts and Nano-structured Materials
二金属和多金属羰基配合物的硫化物和二硫化物:纳米催化剂和纳米结构材料的前体
  • 批准号:
    0354892
  • 财政年份:
    2004
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Continuing Grant
Catalytic Synthesis of Polythioether Macrocycles from Thietanes and Thiiranes
硫杂环丁烷和硫杂丙环催化合成聚硫醚大环化合物
  • 批准号:
    9909017
  • 财政年份:
    2000
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Continuing Grant
Systematics of the Synthesis and Reactivity of Heteronuclear Cluster Compounds
异核簇化合物的合成和反应系统学
  • 批准号:
    9422001
  • 财政年份:
    1995
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Continuing Grant
Systematics of the Synthesis and Reactivity of Heteronuclear Cluster Compounds
异核簇化合物的合成和反应系统学
  • 批准号:
    9224141
  • 财政年份:
    1993
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Continuing Grant

相似海外基金

N-H Reductive Elimination on the Well-defined Polynuclear Transition Metal Complexes
明确多核过渡金属配合物的 N-H 还原消除
  • 批准号:
    15K05459
  • 财政年份:
    2015
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
Magnetic analysis and anisotropy control of polynuclear T-ground-term transition metal complexes
多核T-基项过渡金属配合物的磁分析和各向异性控制
  • 批准号:
    15K05445
  • 财政年份:
    2015
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
Selective Isomerization and Transformation of Aromatic Hydrocarbons by Using Polynuclear Transition Metal Hydride Complexes
多核过渡金属氢化物配合物选择性异构化和芳烃转化
  • 批准号:
    26810041
  • 财政年份:
    2014
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Grant-in-Aid for Young Scientists (B)
Spectroscopy and electron dynamics of polynuclear lanthanide and transition metal complexes (multi-lanthanide) (C05)
多核稀土元素和过渡金属配合物(多稀土元素)的光谱学和电子动力学(C05)
  • 批准号:
    189483018
  • 财政年份:
    2011
  • 资助金额:
    $ 43.5万
  • 项目类别:
    CRC/Transregios
Cooperative Reactivity of Metal Atoms in Polynuclear Transition Metal Polyhydrides (A08)
多核过渡金属氢化物中金属原子的协同反应性(A08)
  • 批准号:
    159663198
  • 财政年份:
    2010
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Collaborative Research Centres
Development of Novel Transformation on Polynuclear Transition Metal Complexes
多核过渡金属配合物的新型转化研究进展
  • 批准号:
    18350048
  • 财政年份:
    2006
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Grant-in-Aid for Scientific Research (B)
Self-assembly, structural and magnetic properties of polynuclear transition metal clusters
多核过渡金属团簇的自组装、结构和磁性
  • 批准号:
    303527-2004
  • 财政年份:
    2006
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Postgraduate Scholarships - Doctoral
Self-assembly, structural and magnetic properties of polynuclear transition metal clusters
多核过渡金属团簇的自组装、结构和磁性
  • 批准号:
    303527-2004
  • 财政年份:
    2005
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Postgraduate Scholarships - Doctoral
Self-assembly, structural and magnetic properties of polynuclear transition metal clusters
多核过渡金属团簇的自组装、结构和磁性
  • 批准号:
    303527-2004
  • 财政年份:
    2004
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Postgraduate Scholarships - Doctoral
Studies on Magnetic Properties of Transition Metal Polynuclear Complexes and Molecular Design Aiming to Single-Molecule Magnets
过渡金属多核配合物磁性能研究及单分子磁体分子设计
  • 批准号:
    14540533
  • 财政年份:
    2002
  • 资助金额:
    $ 43.5万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
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