Unsaturated Heterometallic Cluster Complexes for Hydrogen Activation and Catalytic Hydrogenations

用于氢活化和催化加氢的不饱和异金属簇配合物

• 批准号: 0743190
• 负责人: Richard Adams
• 金额: --
• 依托单位: University South Carolina Research Foundation
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2008
• 资助国家: 美国
• 起止时间: 2008-06-15 至 2011-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0743190&HistoricalAwards=false
• 关键词: Unsaturated; Heterometallic; Cluster; Complexes; Hydrogen

This award by the Inorganic, Bioinorganic, and Organometallic Chemistry Program supports the work of Professor Richard D. Adams at the University of South Carolina to design, synthesize, and characterize new, unsaturated heterometallic complexes for the reversible activation of hydrogen. The exceptionally-active targeted complexes contain platinum or palladium and highly sterically crowded phosphine ligands to induce electronic saturation and reversible hydrogen bonding. This hydrogen activation occurs at mild temperatures and may be important in hydrogen storage as well as in catalytic hydrogenation reactions for the chemical industry. The generation and utilization of hydrogen as an alternative fuel is of growing importance in the emerging hydrogen economy. As Professor Adams contributes rare expertise in both the synthesis and characterization new materials, the graduate and postdoctoral students in his group will gain unique, relevant, and highly valuable learning experiences.

这个奖项由无机，生物无机和有机化学计划支持教授理查德D。南卡罗来纳州大学的亚当斯设计，合成和表征新的，不饱和的异金属络合物的可逆活化氢。 具有特殊活性的靶向配合物含有铂或钯和高度空间拥挤的膦配体，以诱导电子饱和和可逆氢键。这种氢活化在温和的温度下发生，并且在氢储存以及化学工业的催化氢化反应中可能是重要的。 作为替代燃料的氢的产生和利用在新兴的氢经济中越来越重要。 由于亚当斯教授在新材料的合成和表征方面贡献了罕见的专业知识，他所在小组的研究生和博士后学生将获得独特的，相关的和非常宝贵的学习经验。