Crystallization and cooperativity in dynamic supramolecular polymers (A03)

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We investigate the structure formation of biomimetic synthetic macromolecules from either the melt state or the solution state, aiming to understand folding and assembly principles between different segments of a polymer molecule. In the new funding period complex, artificial biomimetic elements will be synthesized by repetitive placement within a synthetic polymer chain, able to adopt specific conformations, dynamically changing from folded (e.g. α-helix, β- fold) to unfolded conformations. The proposed synthetic macromolecules are structurally placed between biological macromolecules and purely synthetic molecules, allowing to understand basic structure-formation and nucleation processes of partially unfolded macromolecules.