RUI: Intramolecular Halogen Bonding in Arylene Ethynylene Structures

RUI：亚芳基亚乙炔结构中的分子内卤素键

• 批准号: 1306284
• 负责人: Nathan Bowling
• 金额: $ 24.82万
• 依托单位: University of Wisconsin-Stevens Point
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2013
• 资助国家: 美国
• 起止时间: 2013-06-15 至 2016-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1306284&HistoricalAwards=false
• 关键词: RUI; Intramolecular; Halogen; Bonding; Arylene

With the support from the Macromolecular, Supramolecular and Nanochemistry Program of the Chemistry Division, Professor Bowling of University of Wisconsin-Stevens Point and Professor Bosch of Missouri State University conduct collaborative research to study the spatial and electronic requirements for intramolecular halogen bonding in solution and the solid state, respectively. Specially, the research team investigates the ability of pyridine-halogen attractions to serve as surrogates for alkynes in dehydroannulene-type materials and the feasibility of extending this strategy to more complex macromolecular species. This research aims to develop strategies for incorporating halogen bonding as a tool for conformation control in conjugated molecules. Conjugated organic molecules are important constituents of functional materials in many useful applications. This research contributes both to increasing our fundamental knowledge and the development of alternative synthetic routes to complex structures with potential applications as functional materials. In addition, this project provides research opportunities to undergraduate students, preparing them for industrial positions and graduate studies.

在化学部高分子、超分子和纳米化学项目的支持下，威斯康星大学史蒂文斯波因特分校的Bowling教授和密苏里州立大学的Bosch教授分别开展了合作研究，分别研究了溶液和固态下分子内卤素键合的空间和电子需求。 特别是，研究小组研究了吡啶-卤素吸引力作为脱氢轮烯型材料中炔烃替代物的能力，以及将该策略扩展到更复杂的大分子物种的可行性。 本研究旨在开发将卤素键合作为共轭分子构象控制工具的策略。 共轭有机分子是许多有用应用中功能材料的重要组成部分。 这项研究既有助于增加我们的基础知识，也有助于开发具有作为功能材料潜在应用的复杂结构的替代合成路线。 此外，该项目还为本科生提供研究机会，为他们担任工业职位和研究生学习做好准备。