Small-Molecule Vapor-Deposited Materials for Integrated Nonlinear Optics

用于集成非线性光学的小分子气相沉积材料

• 批准号: 1408862
• 负责人: Ivan Biaggio
• 金额: $ 37.25万
• 依托单位: Lehigh University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2014
• 资助国家: 美国
• 起止时间: 2014-07-01 至 2019-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1408862&HistoricalAwards=false
• 关键词: Small; Molecule; Vapor; Deposited; Materials

Non-technical Description: Nonlinear optical materials enable the interaction between multiple photons, allowing light signals to control other light signals. Such capabilities are important for continuous developments in optical computing and in optical telecommunication networks such as those that today transmit everything from TV channels to the Internet. This research project aims at studying and developing a new fundamental paradigm that consists in using small organic molecules to build high-quality "plastic" nonlinear optical materials that can then be used with current and future technologies to provide important new all-optical data-processing capabilities at ultrafast speeds. The interdisciplinary nature of the research and its vertically integrated approach (from molecules to materials to devices) provide a varied training ground for the education of undergraduate and graduate students, who learn to use modern laser systems and to control (in wavelength and in time) short optical pulses, while at the same time being exposed to chemistry on one side and engineering on the other.Technical Description: The project aims at advancing the understanding of fundamental nonlinear optical properties and how they translate from molecules to the solid-state, and at creating flexible organic nonlinear optical materials by vapor deposition of optimized molecules into dense supramolecular assemblies with a high optical quality. The research focuses on small molecules where donor-acceptor substitution leads to lower excited state energies and higher third-order polarizabilities, and it exploits the high molecular densities achieved in single-component assemblies to obtain off-resonant third-order nonlinearities in the final bulk materials that are at least three orders of magnitude larger than silica glass. The properties of the molecules, the resulting evaporated materials, and their relationships are studied with a range of nonlinear optical laser spectroscopy techniques and thin-film characterization methods. Optimized molecular designs lead to evaporated materials with a high, glass-like optical quality that can be combined with existing integrated optics technologies, such as silicon photonics, to add active components for applications such as all-optical switching.

非技术描述：非线性光学材料允许多个光子之间的相互作用，允许光信号控制其他光信号。这种能力对于光计算和光通信网络的持续发展非常重要，例如那些今天传输从电视频道到互联网的一切的光通信网络。这一研究项目旨在研究和开发一种新的基本模式，包括使用有机小分子来构建高质量的“塑料”非线性光学材料，然后可以与当前和未来的技术一起使用，以提供重要的新的超高速全光数据处理能力。这项研究的跨学科性质及其垂直整合的方法(从分子到材料再到器件)为本科生和研究生的教育提供了不同的培训基础，他们学习使用现代激光系统和控制(在波长和时间上)短的光脉冲，同时一方面接触化学，另一方面接触工程。技术描述：该项目旨在促进对基本非线性光学性质以及它们如何从分子转化到固态的了解，并通过将优化的分子气相沉积成高光学质量的致密超分子组件来创建灵活的有机非线性光学材料。这项研究的重点是小分子，其中施主-受主取代导致较低的激发态能量和较高的三阶极化率，它利用在单组分组装中获得的高分子密度，在最终的块体材料中获得至少比石英玻璃大三个数量级的非共振三阶非线性。用一系列非线性光学激光光谱技术和薄膜表征方法研究了分子的性质、所产生的蒸发材料以及它们之间的关系。优化的分子设计使蒸发材料具有高玻璃般的光学质量，可以与现有的集成光学技术(如硅光子学)相结合，为全光开关等应用增加有源元件。

项目成果

Optimum conjugation length in donor–acceptor molecules for third-order nonlinear optics

三阶非线性光学供体-受体分子的最佳共轭长度

• DOI: 10.1364/josab.33.00e130
• 发表时间: 2016
• 期刊: Journal of the Optical Society of America B
• 作者: Erickson, Michael A.;Beels, Marten T.;Biaggio, Ivan
• 通讯作者: Biaggio, Ivan