Synthesis of heteronuclear combinations of elements of groups 13 to 15 of the periodic table

分子异核氮化物和磷化物将用异常碳烯和环和无环烷基胺碳烯分离。调查将集中在第13至15组元素上。与正常n -杂环碳相比，异常碳和烷基胺碳具有更强的亲电性和亲核性。因此，分子种类将更好地稳定和更容易分离。所得到的分子异核元素可能在制备半导体材料和催化剂方面具有有趣的性质。作为替代烷基胺碳烯和异常碳烯的一种替代方法，我们提出了钳形分子，这是制备这些体系的一个很好的工具。

Molecular heteronuclear nitrides and phosphides will be isolated using abnormal carbenes and cyclic as well as acyclic alkylamino carbenes. The investigations will concentrate on Groups 13 to 15 elements. The abnormal carbenes and the alkylamino carbenes are more electrophilic and more nucleophilic when compared with normal N-heterocyclic carbenes. The molecular species therefore will be better stabilized and easier isolated. The resulting molecular heteronuclear element species may have interesting properties for the preparation of semi conducting materials and catalysts. As an alternative method for replacing the alkylamino carbenes and abnormal carbenes we propose pincer molecules which are an excellent tool for preparing these systems.