Collaborative Research: Impact of Metals on Photochemical Aging of Water Soluble Organic Carbon in Atmospheric Particulate Matter: A Combined Lab and Field Study

合作研究：金属对大气颗粒物中水溶性有机碳光化学老化的影响：实验室和现场联合研究

• 批准号: 1549387
• 负责人: Michael Hannigan
• 金额: $ 25.42万
• 依托单位: University of Colorado at Boulder
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2016
• 资助国家: 美国
• 起止时间: 2016-04-15 至 2019-09-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1549387&HistoricalAwards=false
• 关键词: Collaborative; Research; Impact; Metals; Photochemical

This study is focused on improving the understanding of the interactions between soluble iron (Fe) and organic material in fine particles in the atmosphere. This research is relevant to the larger question of how atmospheric iron affects the processing and aging of the organics in atmospheric particulate matter. The results will provide information useful to atmospheric chemists and to environmental health professionals.The project will examine the importance of the Fe-assisted oxidation route of water-soluble organic carbon. It consists of three tasks: (1) field sampling, (2) characterization of the particulate matter, and (3) photochemical laboratory experiments. The field samples will be analyzed to assess the sources of the atmospheric Fe, since the source of the Fe may determine its chemical speciation and, thus, its solubility and availability to chemical reactions. Aqueous extracts of the field samples will be subjected to an artificial aging process and undergo analysis for oxidation state and the chemical speciation of total iron, and the production of reactive oxygen species will be quantified. By investigating the role of transition metals and taking into account aqueous chemistry, this project will offer a more complete picture of how organic compounds are "aged" in the atmosphere. The results will provide useful information on the role iron plays in the processing of organic compounds in atmospheric particulate matter and the potential impacts of these mixed particles on human health.

本研究的重点是提高对大气细颗粒物中可溶性铁（Fe）与有机物之间相互作用的认识。 这项研究与大气铁如何影响大气颗粒物中有机物的加工和老化这一更大的问题有关。 研究结果将为大气化学家和环境卫生专业人员提供有用的信息。该项目将研究铁辅助水溶性有机碳氧化途径的重要性。它包括三个任务：（1）现场采样，（2）颗粒物的表征，（3）光化学实验室实验。 将对现场样品进行分析，以评估大气Fe的来源，因为Fe的来源可能决定其化学形态，从而决定其溶解度和化学反应的可用性。 将对现场样品的水提取物进行人工老化处理，并对氧化态和总铁的化学形态进行分析，并对活性氧的产生进行量化。通过调查过渡金属的作用并考虑到水化学，该项目将提供有机化合物如何在大气中“老化”的更完整的画面。 研究结果将为铁在大气颗粒物中有机化合物的处理中所起的作用以及这些混合颗粒物对人类健康的潜在影响提供有用的信息。