Highly Active Neodymium Catalysts for Polymerization of Dienes and Vinyl Monomers

用于二烯和乙烯基单体聚合的高活性钕催化剂

• 批准号: 1566059
• 负责人: Mihaela Stefan
• 金额: $ 37.5万
• 依托单位: University of Texas at Dallas
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2016
• 资助国家: 美国
• 起止时间: 2016-09-01 至 2021-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1566059&HistoricalAwards=false
• 关键词: Highly; Active; Neodymium; Catalysts; Polymerization

Professor Mihaela C. Stefan of the University of Texas at Dallas is supported by the Chemical Catalysis Program of the Division of Chemistry to develop polymerization catalysts based on neodymium (Nd) metal complexes. The objective is to provide research laboratories and the chemical industry with an alternative for the well-known Ziegler-Natta (ZN) catalyst system, which is widely used in industry for the preparation of polymers (large multi-unit molecules) from smaller molecules. The proposed Nd-based catalytic systems have the advantage of producing polymers from unusual starting materials, in reactions that are beyond the capabilities of current ZN catalysts. The versatile nature of the Nd-based catalytic system enhances the likelihood of success for the synthesis of stereoregular (highly ordered) polymers from different classes of small organic compounds. If successful, the project is likely to have immediate impact on the commercial production of polymeric materials, such as elastomers, adhesives and man-made fibers. Students working on the project are trained in organic and polymer synthesis and product characterization techniques. Female high school students are given the opportunity to participate in summer research to gain skills in a chemistry laboratory environment.The objective of this research is to develop a novel catalytic system composed of NdCl3 and phosphate ligands for the polymerization of a variety of monomers, such as dienes, styrene and polar vinyl monomers. A mechanistic investigation of these polymerizations will be conducted to understand the function of each component and to optimize the reaction conditions for the production of polymers with high stereoregularity and well-defined molecular weights. The variation of the phosphate ligands around the Nd metal center is expected to influence the stereoregularity, molecular weights, and polydispersities of the synthesized polymers. The crystal structures of the synthesized neodymium catalysts is determined and correlated with their catalytic activity. The use of these catalysts for copolymerization of dienes with polar vinyl monomers demonstrates the versatility of the neodymium catalytic systems. The ability to polymerize polar vinyl monomers is especially attractive because the conventional Ziegler-Natta catalysts are not active for polymerization of polar vinyl monomers.

Mihaela C.教授德克萨斯大学达拉斯分校的Stefan在化学系化学催化项目的支持下开发了基于钕（Nd）金属配合物的聚合催化剂。 目的是为研究实验室和化学工业提供众所周知的齐格勒-纳塔（ZN）催化剂体系的替代方案，该催化剂体系在工业中广泛用于从较小分子制备聚合物（大的多单元分子）。 所提出的Nd基催化体系具有在超出当前ZN催化剂能力的反应中从不寻常的起始材料生产聚合物的优点。 Nd基催化体系的多功能性提高了从不同种类的小有机化合物合成有规立构（高度有序）聚合物的成功可能性。 如果成功，该项目可能会对聚合物材料的商业生产产生直接影响，如弹性体，粘合剂和人造纤维。 从事该项目的学生接受有机和聚合物合成以及产品表征技术的培训。 高中女生有机会参加暑期研究，在化学实验室环境中获得技能。本研究的目的是开发一种新型的催化体系，由NdCl 3和磷酸盐配体组成，用于多种单体的聚合，如二烯烃，苯乙烯和极性乙烯基单体。将进行这些聚合的机理研究，以了解每个组分的功能，并优化生产具有高立构规整性和明确分子量的聚合物的反应条件。预计钕金属中心周围的磷酸盐配体的变化会影响合成的聚合物的立构规整性、分子量和多分散性。测定了合成的钕催化剂的晶体结构，并与其催化活性进行了关联。 这些催化剂用于二烯与极性乙烯基单体的共聚，证明了钕催化体系的多功能性。由于常规齐格勒-纳塔催化剂对极性乙烯基单体的聚合没有活性，因此使极性乙烯基单体聚合的能力特别有吸引力。